Factors that determine thione(thiol)-disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex

Haewon Jeong; Yeji Kang; Jin Kim; Byung Kwon Kim; Seungwoo Hong

doi:10.1039/c9ra01115c

Factors that determine thione(thiol)-disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex

Haewon Jeong, Yeji Kang, Jin Kim, Byung Kwon Kim, Seungwoo Hong

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Solvent-, acidity-, and redox-responsive thione(thiol)-disulfide interconversion were achieved by a dinuclear copper(ii) complex bearing a bis(thiosemicarbazone) (bTSC) ligand. The role of copper(ii) ion coordination was rationalized by parallel comparison with a bare bTSC ligand and zinc(ii) bTSC complexes under identical reaction conditions.

Original language	English
Pages (from-to)	9049-9052
Number of pages	4
Journal	RSC Advances
Volume	9
Issue number	16
DOIs	https://doi.org/10.1039/c9ra01115c
State	Published - 2019

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© 2019 The Royal Society of Chemistry.

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abstract = "Solvent-, acidity-, and redox-responsive thione(thiol)-disulfide interconversion were achieved by a dinuclear copper(ii) complex bearing a bis(thiosemicarbazone) (bTSC) ligand. The role of copper(ii) ion coordination was rationalized by parallel comparison with a bare bTSC ligand and zinc(ii) bTSC complexes under identical reaction conditions.",

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AU - Jeong, Haewon

AU - Kang, Yeji

AU - Kim, Jin

AU - Kim, Byung Kwon

AU - Hong, Seungwoo

PY - 2019

Y1 - 2019

N2 - Solvent-, acidity-, and redox-responsive thione(thiol)-disulfide interconversion were achieved by a dinuclear copper(ii) complex bearing a bis(thiosemicarbazone) (bTSC) ligand. The role of copper(ii) ion coordination was rationalized by parallel comparison with a bare bTSC ligand and zinc(ii) bTSC complexes under identical reaction conditions.

AB - Solvent-, acidity-, and redox-responsive thione(thiol)-disulfide interconversion were achieved by a dinuclear copper(ii) complex bearing a bis(thiosemicarbazone) (bTSC) ligand. The role of copper(ii) ion coordination was rationalized by parallel comparison with a bare bTSC ligand and zinc(ii) bTSC complexes under identical reaction conditions.

UR - https://www.scopus.com/pages/publications/85063317985

U2 - 10.1039/c9ra01115c

DO - 10.1039/c9ra01115c

M3 - Article

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SN - 2046-2069

VL - 9

SP - 9049

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JO - RSC Advances

JF - RSC Advances

IS - 16

ER -

Factors that determine thione(thiol)-disulfide interconversion in a bis(thiosemicarbazone) copper(ii) complex

Abstract

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