Evidence that gold(III) porphyrins are not electrochemically inert: Facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

Karl M. Kadish; E. Wenbo; Zhongping Ou; Jianguo Shao; Paul J. Sintic; Kei Ohkubo; Shunichi Fukuzumi; Maxwell J. Crossley

doi:10.1039/b109795d

Evidence that gold(III) porphyrins are not electrochemically inert: Facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

Karl M. Kadish
, E. Wenbo
, Zhongping Ou
, Jianguo Shao
, Paul J. Sintic
, Kei Ohkubo
, Shunichi Fukuzumi
, Maxwell J. Crossley

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

Gold(III) porphyrin 1 is shown to undergo reduction at the central metal ion to give the first known gold(II) porphyrin overturning the long held assumption that reduction of such complexes only occurs at the macrocycle.

Original language	English
Pages (from-to)	356-357
Number of pages	2
Journal	Chemical Communications
Volume	4
DOIs	https://doi.org/10.1039/b109795d
State	Published - 21 Feb 2002

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title = "Evidence that gold(III) porphyrins are not electrochemically inert: Facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin",

abstract = "Gold(III) porphyrin 1 is shown to undergo reduction at the central metal ion to give the first known gold(II) porphyrin overturning the long held assumption that reduction of such complexes only occurs at the macrocycle.",

author = "Kadish, \{Karl M.\} and E. Wenbo and Zhongping Ou and Jianguo Shao and Sintic, \{Paul J.\} and Kei Ohkubo and Shunichi Fukuzumi and Crossley, \{Maxwell J.\}",

year = "2002",

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doi = "10.1039/b109795d",

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journal = "Chemical Communications",

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T1 - Evidence that gold(III) porphyrins are not electrochemically inert

T2 - Facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

AU - Kadish, Karl M.

AU - Wenbo, E.

AU - Ou, Zhongping

AU - Shao, Jianguo

AU - Sintic, Paul J.

AU - Ohkubo, Kei

AU - Fukuzumi, Shunichi

AU - Crossley, Maxwell J.

PY - 2002/2/21

Y1 - 2002/2/21

N2 - Gold(III) porphyrin 1 is shown to undergo reduction at the central metal ion to give the first known gold(II) porphyrin overturning the long held assumption that reduction of such complexes only occurs at the macrocycle.

AB - Gold(III) porphyrin 1 is shown to undergo reduction at the central metal ion to give the first known gold(II) porphyrin overturning the long held assumption that reduction of such complexes only occurs at the macrocycle.

UR - https://www.scopus.com/pages/publications/0037148825

U2 - 10.1039/b109795d

DO - 10.1039/b109795d

M3 - Article

C2 - 12120072

AN - SCOPUS:0037148825

SN - 1359-7345

VL - 4

SP - 356

EP - 357

JO - Chemical Communications

JF - Chemical Communications

ER -

Evidence that gold(III) porphyrins are not electrochemically inert: Facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

Abstract

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