Evaporation-induced self-assembly of trans-2-aminocyclopentanecarboxylic acid hexamers

Sunbum Kwon; Kyungtae Kang; Aram Jeon; Ji Hun Park; Insung S. Choi; Hee Seung Lee

doi:10.1016/j.tet.2012.02.061

Evaporation-induced self-assembly of trans-2-aminocyclopentanecarboxylic acid hexamers

Sunbum Kwon, Kyungtae Kang, Aram Jeon, Ji Hun Park, Insung S. Choi, Hee Seung Lee

Department of Science Education

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

In this paper, we report the self-assembly phenomenon of trans-2-aminocyclopentanecarboxylic acid hexamer (ACPC ₆) by the evaporation-induced self-assembly. The SEM and TEM analyses of the self-assembled 3D molecular architecture revealed the characteristic shape of hollow parallelepiped and its supramolecular chiral expression on surface. A systematic study with the derivatives of ACPC ₆ showed the effect of the terminal groups of ACPC ₆ on the particular 3D shape formation. We also found that water molecules played a crucial role in the formation of hollow morphogenesis under the evaporation-induced self-assembly condition, and a plausible formation mechanism was suggested.

Original language	English
Pages (from-to)	4368-4373
Number of pages	6
Journal	Tetrahedron
Volume	68
Issue number	23
DOIs	https://doi.org/10.1016/j.tet.2012.02.061
State	Published - 10 Jun 2012

Bibliographical note

Funding Information:
This work was supported by a Basic Science Research Program of the National Research Foundation of Korea (NRF) grant funded by the Ministry of Education, Science and Technology ( 2009-0084449, 2011-0012141 , and 2011-0001318 ).

Keywords

Foldamer
Nanostructure
Self-assembly
β-Peptide

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10.1016/j.tet.2012.02.061

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title = "Evaporation-induced self-assembly of trans-2-aminocyclopentanecarboxylic acid hexamers",

abstract = "In this paper, we report the self-assembly phenomenon of trans-2-aminocyclopentanecarboxylic acid hexamer (ACPC 6) by the evaporation-induced self-assembly. The SEM and TEM analyses of the self-assembled 3D molecular architecture revealed the characteristic shape of hollow parallelepiped and its supramolecular chiral expression on surface. A systematic study with the derivatives of ACPC 6 showed the effect of the terminal groups of ACPC 6 on the particular 3D shape formation. We also found that water molecules played a crucial role in the formation of hollow morphogenesis under the evaporation-induced self-assembly condition, and a plausible formation mechanism was suggested.",

keywords = "Foldamer, Nanostructure, Self-assembly, β-Peptide",

author = "Sunbum Kwon and Kyungtae Kang and Aram Jeon and Park, {Ji Hun} and Choi, {Insung S.} and Lee, {Hee Seung}",

note = "Funding Information: This work was supported by a Basic Science Research Program of the National Research Foundation of Korea (NRF) grant funded by the Ministry of Education, Science and Technology ( 2009-0084449, 2011-0012141 , and 2011-0001318 ).",

year = "2012",

month = jun,

day = "10",

doi = "10.1016/j.tet.2012.02.061",

language = "English",

volume = "68",

pages = "4368--4373",

journal = "Tetrahedron",

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T1 - Evaporation-induced self-assembly of trans-2-aminocyclopentanecarboxylic acid hexamers

AU - Kwon, Sunbum

AU - Kang, Kyungtae

AU - Jeon, Aram

AU - Park, Ji Hun

AU - Choi, Insung S.

AU - Lee, Hee Seung

N1 - Funding Information: This work was supported by a Basic Science Research Program of the National Research Foundation of Korea (NRF) grant funded by the Ministry of Education, Science and Technology ( 2009-0084449, 2011-0012141 , and 2011-0001318 ).

PY - 2012/6/10

Y1 - 2012/6/10

N2 - In this paper, we report the self-assembly phenomenon of trans-2-aminocyclopentanecarboxylic acid hexamer (ACPC 6) by the evaporation-induced self-assembly. The SEM and TEM analyses of the self-assembled 3D molecular architecture revealed the characteristic shape of hollow parallelepiped and its supramolecular chiral expression on surface. A systematic study with the derivatives of ACPC 6 showed the effect of the terminal groups of ACPC 6 on the particular 3D shape formation. We also found that water molecules played a crucial role in the formation of hollow morphogenesis under the evaporation-induced self-assembly condition, and a plausible formation mechanism was suggested.

AB - In this paper, we report the self-assembly phenomenon of trans-2-aminocyclopentanecarboxylic acid hexamer (ACPC 6) by the evaporation-induced self-assembly. The SEM and TEM analyses of the self-assembled 3D molecular architecture revealed the characteristic shape of hollow parallelepiped and its supramolecular chiral expression on surface. A systematic study with the derivatives of ACPC 6 showed the effect of the terminal groups of ACPC 6 on the particular 3D shape formation. We also found that water molecules played a crucial role in the formation of hollow morphogenesis under the evaporation-induced self-assembly condition, and a plausible formation mechanism was suggested.

KW - Foldamer

KW - Nanostructure

KW - Self-assembly

KW - β-Peptide

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U2 - 10.1016/j.tet.2012.02.061

DO - 10.1016/j.tet.2012.02.061

M3 - Article

AN - SCOPUS:84862830173

SN - 0040-4020

VL - 68

SP - 4368

EP - 4373

JO - Tetrahedron

JF - Tetrahedron

IS - 23

ER -

Evaporation-induced self-assembly of trans-2-aminocyclopentanecarboxylic acid hexamers

Abstract

Bibliographical note

Keywords

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