TY - JOUR
T1 - Evaluation of metal-supported solid oxide fuel cells (MS-SOFCs) fabricated at low temperature (∼1,000 °C) using wet chemical coating processes and a catalyst wet impregnation method
AU - Lee, Kunho
AU - Kang, Juhyun
AU - Lee, Jaeseok
AU - Lee, Sanghun
AU - Bae, Joongmyeon
N1 - Publisher Copyright:
© 2018 Hydrogen Energy Publications LLC
PY - 2018/2/15
Y1 - 2018/2/15
N2 - The objective of this study is to evaluate metal-supported solid oxide fuel cells fabricated at low temperatures (∼1000 °C) in oxidizing environments using wet chemical coating processes and a catalyst impregnation method. Typically, applying general wet chemical coating processes and heat treatment at low temperature is desirable for fabricating metal-supported solid oxide fuel cells when considering manufacturing productivity and efficiency. However, in the case of conventional anodes, a well-organized structure for high performance is rarely formed by sintering at low temperatures when using general fabrication processes. For this reason, a catalyst-impregnated anode is designed and applied to overcome the above issue. First, to evaluate the electrochemical performance of the designed anode, the area-specific resistances of half-cells are investigated. Then, the newly designed anode is applied to a single cell, and microstructural analysis and electrochemical performance measurements are performed. These results confirm that the catalysts are well distributed, that the electrolyte is fully dense and that the electrochemical performances are reasonable. Additionally, the high durability is also verified through a long-term test over 1000 h. Finally, the metal-supported solid oxide fuel cell with a catalyst-impregnated anode fabricated at low temperature is completely validated through the evaluation of a large-size single cell.
AB - The objective of this study is to evaluate metal-supported solid oxide fuel cells fabricated at low temperatures (∼1000 °C) in oxidizing environments using wet chemical coating processes and a catalyst impregnation method. Typically, applying general wet chemical coating processes and heat treatment at low temperature is desirable for fabricating metal-supported solid oxide fuel cells when considering manufacturing productivity and efficiency. However, in the case of conventional anodes, a well-organized structure for high performance is rarely formed by sintering at low temperatures when using general fabrication processes. For this reason, a catalyst-impregnated anode is designed and applied to overcome the above issue. First, to evaluate the electrochemical performance of the designed anode, the area-specific resistances of half-cells are investigated. Then, the newly designed anode is applied to a single cell, and microstructural analysis and electrochemical performance measurements are performed. These results confirm that the catalysts are well distributed, that the electrolyte is fully dense and that the electrochemical performances are reasonable. Additionally, the high durability is also verified through a long-term test over 1000 h. Finally, the metal-supported solid oxide fuel cell with a catalyst-impregnated anode fabricated at low temperature is completely validated through the evaluation of a large-size single cell.
KW - Catalyst impregnation method
KW - Metal-supported SOFC
KW - Ni-impregnated LST-GDC
KW - Perforated Crofer 22 APU
KW - Wet chemical coating process
UR - http://www.scopus.com/inward/record.url?scp=85040964926&partnerID=8YFLogxK
U2 - 10.1016/j.ijhydene.2018.01.027
DO - 10.1016/j.ijhydene.2018.01.027
M3 - Article
AN - SCOPUS:85040964926
SN - 0360-3199
VL - 43
SP - 3786
EP - 3796
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
IS - 7
ER -