Electronic switch of metal conductivity in μ6-carbon centered [Re12(μ6-C)S17(CN)6] n- nano cluster

V. E. Fedorov; S. P. Gabuda; S. G. Kozlova; Y. V. Mironov; N. G. Naumov; S. J. Kim; N. F. Zakharchuk

Electronic switch of metal conductivity in μ₆-carbon centered [Re₁₂(μ₆-C)S₁₇(CN)₆] ^n- nano cluster

V. E. Fedorov, S. P. Gabuda, S. G. Kozlova, Y. V. Mironov, N. G. Naumov, S. J. Kim, N. F. Zakharchuk

Department of Chemistry & Nanoscience

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

2 Scopus citations

Abstract

The unique dodecanuclear cluster compounds M_n[Re ₁₂(μ₆-C)S₁₇(CN)₆] (M-alkali metal; n=6, 8) were prepared and studied by cyclic voltammetry, solid-state high-resolution ¹³C NMR and by density functional theory (DFT). The change of the anion redox state is accompanied by essential jump of distance between two {Re₆} subunits in a carbon-centered bioctahedral fragment [Re₆-C-Re₆] of the cluster. Switching of metal conductivity off and on is evidenced by giant change of ¹³C NMR shielding that is typical for metal to insulator phase transitions.

Original language	English
Title of host publication	MIPRO 2010 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, Proceedings
Pages	3-5
Number of pages	3
State	Published - 2010
Event	33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, MIPRO 2010 - Opatija, Croatia Duration: 24 May 2010 → 28 May 2010

Publication series

Name	MIPRO 2010 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, Proceedings

Conference

Conference	33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, MIPRO 2010
Country/Territory	Croatia
City	Opatija
Period	24/05/10 → 28/05/10

Cite this

Fedorov, V. E., Gabuda, S. P., Kozlova, S. G., Mironov, Y. V., Naumov, N. G., Kim, S. J., & Zakharchuk, N. F. (2010). Electronic switch of metal conductivity in μ₆-carbon centered [Re₁₂(μ₆-C)S₁₇(CN)₆] ^n- nano cluster. In MIPRO 2010 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, Proceedings (pp. 3-5). Article 5533708 (MIPRO 2010 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, Proceedings).

Fedorov, V. E. ; Gabuda, S. P. ; Kozlova, S. G. et al. / Electronic switch of metal conductivity in μ₆-carbon centered [Re₁₂(μ₆-C)S₁₇(CN)₆] ^n- nano cluster. MIPRO 2010 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, Proceedings. 2010. pp. 3-5 (MIPRO 2010 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, Proceedings).

@inproceedings{33ac858648b34b7d8ee567f347f851b6,

title = "Electronic switch of metal conductivity in μ6-carbon centered [Re12(μ6-C)S17(CN)6] n- nano cluster",

abstract = "The unique dodecanuclear cluster compounds Mn[Re 12(μ6-C)S17(CN)6] (M-alkali metal; n=6, 8) were prepared and studied by cyclic voltammetry, solid-state high-resolution 13C NMR and by density functional theory (DFT). The change of the anion redox state is accompanied by essential jump of distance between two {Re6} subunits in a carbon-centered bioctahedral fragment [Re6-C-Re6] of the cluster. Switching of metal conductivity off and on is evidenced by giant change of 13C NMR shielding that is typical for metal to insulator phase transitions.",

author = "Fedorov, {V. E.} and Gabuda, {S. P.} and Kozlova, {S. G.} and Mironov, {Y. V.} and Naumov, {N. G.} and Kim, {S. J.} and Zakharchuk, {N. F.}",

year = "2010",

language = "English",

isbn = "9789532330502",

series = "MIPRO 2010 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, Proceedings",

pages = "3--5",

booktitle = "MIPRO 2010 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, Proceedings",

note = "33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, MIPRO 2010 ; Conference date: 24-05-2010 Through 28-05-2010",

}

Fedorov, VE, Gabuda, SP, Kozlova, SG, Mironov, YV, Naumov, NG, Kim, SJ & Zakharchuk, NF 2010, Electronic switch of metal conductivity in μ₆-carbon centered [Re₁₂(μ₆-C)S₁₇(CN)₆] ^n- nano cluster. in MIPRO 2010 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, Proceedings., 5533708, MIPRO 2010 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, Proceedings, pp. 3-5, 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, MIPRO 2010, Opatija, Croatia, 24/05/10.

Electronic switch of metal conductivity in μ₆-carbon centered [Re₁₂(μ₆-C)S₁₇(CN)₆] ^n- nano cluster. / Fedorov, V. E.; Gabuda, S. P.; Kozlova, S. G. et al.
MIPRO 2010 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, Proceedings. 2010. p. 3-5 5533708 (MIPRO 2010 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, Proceedings).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Electronic switch of metal conductivity in μ6-carbon centered [Re12(μ6-C)S17(CN)6] n- nano cluster

AU - Fedorov, V. E.

AU - Gabuda, S. P.

AU - Kozlova, S. G.

AU - Mironov, Y. V.

AU - Naumov, N. G.

AU - Kim, S. J.

AU - Zakharchuk, N. F.

PY - 2010

Y1 - 2010

N2 - The unique dodecanuclear cluster compounds Mn[Re 12(μ6-C)S17(CN)6] (M-alkali metal; n=6, 8) were prepared and studied by cyclic voltammetry, solid-state high-resolution 13C NMR and by density functional theory (DFT). The change of the anion redox state is accompanied by essential jump of distance between two {Re6} subunits in a carbon-centered bioctahedral fragment [Re6-C-Re6] of the cluster. Switching of metal conductivity off and on is evidenced by giant change of 13C NMR shielding that is typical for metal to insulator phase transitions.

AB - The unique dodecanuclear cluster compounds Mn[Re 12(μ6-C)S17(CN)6] (M-alkali metal; n=6, 8) were prepared and studied by cyclic voltammetry, solid-state high-resolution 13C NMR and by density functional theory (DFT). The change of the anion redox state is accompanied by essential jump of distance between two {Re6} subunits in a carbon-centered bioctahedral fragment [Re6-C-Re6] of the cluster. Switching of metal conductivity off and on is evidenced by giant change of 13C NMR shielding that is typical for metal to insulator phase transitions.

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M3 - Conference contribution

AN - SCOPUS:77956371981

SN - 9789532330502

T3 - MIPRO 2010 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, Proceedings

SP - 3

EP - 5

BT - MIPRO 2010 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, Proceedings

T2 - 33rd International Convention on Information and Communication Technology, Electronics and Microelectronics, MIPRO 2010

Y2 - 24 May 2010 through 28 May 2010

ER -