Electronic properties of trifluoromethylated corannulenes

Bernd M. Schmidt; Shu Seki; Berit Topolinski; Kei Ohkubo; Shunichi Fukuzumi; Hidehiro Sakurai; Dieter Lentz

doi:10.1002/anie.201205757

Electronic properties of trifluoromethylated corannulenes

Bernd M. Schmidt
, Shu Seki
, Berit Topolinski
, Kei Ohkubo
, Shunichi Fukuzumi
, Hidehiro Sakurai
, Dieter Lentz

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

112 Scopus citations

Abstract

With great stacking comes great conductivity: Trifluoromethylated corannulenes are unexpectedly strong electron acceptors in solution. Even a polycrystalline film of 1,2-(F ₃C) ₂-corannulene (top structure and curve in the plot) exhibits conductivity three orders of magnitude higher than that of pristine corannulene!

Original language	English
Pages (from-to)	11385-11388
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	45
DOIs	https://doi.org/10.1002/anie.201205757
State	Published - 5 Nov 2012

Keywords

buckybowls
corannulenes
electrochemistry
fluorinated compounds
supramolecular chemistry

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10.1002/anie.201205757

Cite this

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abstract = "With great stacking comes great conductivity: Trifluoromethylated corannulenes are unexpectedly strong electron acceptors in solution. Even a polycrystalline film of 1,2-(F 3C) 2-corannulene (top structure and curve in the plot) exhibits conductivity three orders of magnitude higher than that of pristine corannulene!",

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AU - Schmidt, Bernd M.

AU - Seki, Shu

AU - Topolinski, Berit

AU - Ohkubo, Kei

AU - Fukuzumi, Shunichi

AU - Sakurai, Hidehiro

AU - Lentz, Dieter

PY - 2012/11/5

Y1 - 2012/11/5

N2 - With great stacking comes great conductivity: Trifluoromethylated corannulenes are unexpectedly strong electron acceptors in solution. Even a polycrystalline film of 1,2-(F 3C) 2-corannulene (top structure and curve in the plot) exhibits conductivity three orders of magnitude higher than that of pristine corannulene!

AB - With great stacking comes great conductivity: Trifluoromethylated corannulenes are unexpectedly strong electron acceptors in solution. Even a polycrystalline film of 1,2-(F 3C) 2-corannulene (top structure and curve in the plot) exhibits conductivity three orders of magnitude higher than that of pristine corannulene!

KW - buckybowls

KW - corannulenes

KW - electrochemistry

KW - fluorinated compounds

KW - supramolecular chemistry

UR - https://www.scopus.com/pages/publications/84868112666

U2 - 10.1002/anie.201205757

DO - 10.1002/anie.201205757

M3 - Article

AN - SCOPUS:84868112666

SN - 1433-7851

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 45

ER -

Electronic properties of trifluoromethylated corannulenes

Abstract

Keywords

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