Electronic properties of trifluoromethylated corannulenes

Bernd M. Schmidt, Shu Seki, Berit Topolinski, Kei Ohkubo, Shunichi Fukuzumi, Hidehiro Sakurai, Dieter Lentz

Research output: Contribution to journalArticlepeer-review

105 Scopus citations

Abstract

With great stacking comes great conductivity: Trifluoromethylated corannulenes are unexpectedly strong electron acceptors in solution. Even a polycrystalline film of 1,2-(F 3C) 2-corannulene (top structure and curve in the plot) exhibits conductivity three orders of magnitude higher than that of pristine corannulene!

Original languageEnglish
Pages (from-to)11385-11388
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number45
DOIs
StatePublished - 5 Nov 2012

Keywords

  • buckybowls
  • corannulenes
  • electrochemistry
  • fluorinated compounds
  • supramolecular chemistry

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