Electronic properties of trifluoromethylated corannulenes

Bernd M. Schmidt; Shu Seki; Berit Topolinski; Kei Ohkubo; Shunichi Fukuzumi; Hidehiro Sakurai; Dieter Lentz

doi:10.1002/anie.201205757

Electronic properties of trifluoromethylated corannulenes

Bernd M. Schmidt, Shu Seki, Berit Topolinski, Kei Ohkubo, Shunichi Fukuzumi, Hidehiro Sakurai, Dieter Lentz

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

107 Scopus citations

Abstract

With great stacking comes great conductivity: Trifluoromethylated corannulenes are unexpectedly strong electron acceptors in solution. Even a polycrystalline film of 1,2-(F ₃C) ₂-corannulene (top structure and curve in the plot) exhibits conductivity three orders of magnitude higher than that of pristine corannulene!

Original language	English
Pages (from-to)	11385-11388
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	45
DOIs	https://doi.org/10.1002/anie.201205757
State	Published - 5 Nov 2012

Keywords

buckybowls
corannulenes
electrochemistry
fluorinated compounds
supramolecular chemistry

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AU - Seki, Shu

AU - Topolinski, Berit

AU - Ohkubo, Kei

AU - Fukuzumi, Shunichi

AU - Sakurai, Hidehiro

AU - Lentz, Dieter

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KW - buckybowls

KW - corannulenes

KW - electrochemistry

KW - fluorinated compounds

KW - supramolecular chemistry

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M3 - Article

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Electronic properties of trifluoromethylated corannulenes

Abstract

Keywords

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