Electron-transfer reduction of cup-stacked carbon nanotubes affording cup-shaped carbons with controlled diameter and size

Kenji Saito; Masataka Ohtani; Shunichi Fukuzumi

doi:10.1021/ja064300d

Electron-transfer reduction of cup-stacked carbon nanotubes affording cup-shaped carbons with controlled diameter and size

Kenji Saito
, Masataka Ohtani
, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

The electron-transfer reduction of cup-stacked carbon nanotubes (CSCNTs) with sodium naphthalenide and the subsequent treatment with 1-iodododecane results in electrostatically destacking of CSCNTs to afford cup-shaped carbons with controlled diameter and size. The dodecylated cup-shaped carbons were highly dispersed and stable in nonpolar solvents, such as THF, tetrachloroethylene, and chloroform, as compared with the pristine CSCNTs.

Original language	English
Pages (from-to)	14216-14217
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	44
DOIs	https://doi.org/10.1021/ja064300d
State	Published - 8 Nov 2006

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abstract = "The electron-transfer reduction of cup-stacked carbon nanotubes (CSCNTs) with sodium naphthalenide and the subsequent treatment with 1-iodododecane results in electrostatically destacking of CSCNTs to afford cup-shaped carbons with controlled diameter and size. The dodecylated cup-shaped carbons were highly dispersed and stable in nonpolar solvents, such as THF, tetrachloroethylene, and chloroform, as compared with the pristine CSCNTs.",

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AU - Fukuzumi, Shunichi

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Y1 - 2006/11/8

N2 - The electron-transfer reduction of cup-stacked carbon nanotubes (CSCNTs) with sodium naphthalenide and the subsequent treatment with 1-iodododecane results in electrostatically destacking of CSCNTs to afford cup-shaped carbons with controlled diameter and size. The dodecylated cup-shaped carbons were highly dispersed and stable in nonpolar solvents, such as THF, tetrachloroethylene, and chloroform, as compared with the pristine CSCNTs.

AB - The electron-transfer reduction of cup-stacked carbon nanotubes (CSCNTs) with sodium naphthalenide and the subsequent treatment with 1-iodododecane results in electrostatically destacking of CSCNTs to afford cup-shaped carbons with controlled diameter and size. The dodecylated cup-shaped carbons were highly dispersed and stable in nonpolar solvents, such as THF, tetrachloroethylene, and chloroform, as compared with the pristine CSCNTs.

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M3 - Article

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Electron-transfer reduction of cup-stacked carbon nanotubes affording cup-shaped carbons with controlled diameter and size

Abstract

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