Electron transfer reduction of a highly electron-deficient fullerene, C60F18

Kei Ohkubo; Roger Taylor; Olga V. Boltalina; Seiji Ogo; Shunichi Fukuzumi

doi:10.1039/b205642a

Electron transfer reduction of a highly electron-deficient fullerene, C₆₀F₁₈

Kei Ohkubo, Roger Taylor, Olga V. Boltalina, Seiji Ogo, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Electron transfer reduction of a highly electron-deficient fullerene, C₆₀F₁₈, to the defluorinated anion, C₆₀F_17- occurs efficiently by a relatively weak one-electron reductant, p-chloranil radical anion; the one-electron reduction potential of C₆₀F₁₈ is evaluated as 0.04 V (vs. SCE) by comparison of the rate constant for electron-transfer from 10,10′-dimethyl-9,9′,10,10′-tetrahydro-9,9′- biacridine to C₆₀F₁₈ with those of other one-electron reductants.

Original language	English
Pages (from-to)	1952-1953
Number of pages	2
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/b205642a
State	Published - 2002

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title = "Electron transfer reduction of a highly electron-deficient fullerene, C60F18",

abstract = "Electron transfer reduction of a highly electron-deficient fullerene, C60F18, to the defluorinated anion, C60F17- occurs efficiently by a relatively weak one-electron reductant, p-chloranil radical anion; the one-electron reduction potential of C60F18 is evaluated as 0.04 V (vs. SCE) by comparison of the rate constant for electron-transfer from 10,10′-dimethyl-9,9′,10,10′-tetrahydro-9,9′- biacridine to C60F18 with those of other one-electron reductants.",

author = "Kei Ohkubo and Roger Taylor and Boltalina, {Olga V.} and Seiji Ogo and Shunichi Fukuzumi",

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journal = "Chemical Communications",

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T1 - Electron transfer reduction of a highly electron-deficient fullerene, C60F18

AU - Ohkubo, Kei

AU - Taylor, Roger

AU - Boltalina, Olga V.

AU - Ogo, Seiji

AU - Fukuzumi, Shunichi

PY - 2002

Y1 - 2002

N2 - Electron transfer reduction of a highly electron-deficient fullerene, C60F18, to the defluorinated anion, C60F17- occurs efficiently by a relatively weak one-electron reductant, p-chloranil radical anion; the one-electron reduction potential of C60F18 is evaluated as 0.04 V (vs. SCE) by comparison of the rate constant for electron-transfer from 10,10′-dimethyl-9,9′,10,10′-tetrahydro-9,9′- biacridine to C60F18 with those of other one-electron reductants.

AB - Electron transfer reduction of a highly electron-deficient fullerene, C60F18, to the defluorinated anion, C60F17- occurs efficiently by a relatively weak one-electron reductant, p-chloranil radical anion; the one-electron reduction potential of C60F18 is evaluated as 0.04 V (vs. SCE) by comparison of the rate constant for electron-transfer from 10,10′-dimethyl-9,9′,10,10′-tetrahydro-9,9′- biacridine to C60F18 with those of other one-electron reductants.

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U2 - 10.1039/b205642a

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EP - 1953

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Electron transfer reduction of a highly electron-deficient fullerene, C60F18

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Electron transfer reduction of a highly electron-deficient fullerene, C₆₀F₁₈