Electron-transfer properties of an efficient nonheme iron oxidation catalyst with a tetradentate bispidine ligand

Peter Comba; Shunichi Fukuzumi; Hiroaki Kotani; Steffen Wunderlich

doi:10.1002/anie.200904427

Electron-transfer properties of an efficient nonheme iron oxidation catalyst with a tetradentate bispidine ligand

Peter Comba, Shunichi Fukuzumi, Hiroaki Kotani, Steffen Wunderlich

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

74 Scopus citations

Abstract

(Graph Presentation) The oxidation catalyst [ (L) Fe^IV=O] (see picture; L is a tetradentate bispidine ligand) has the highest known one-electron reduction potential for a Fe^IV=O species (0.73 V vs. SCE). Investigations into the electron-transfer kinetics show a linear correlation with the bond dissociation energy of the organic substrates.

Original language	English
Pages (from-to)	2622-2625
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	14
DOIs	https://doi.org/10.1002/anie.200904427
State	Published - 29 Mar 2010

Keywords

Bioinorganic chemistry
C-H activation
Electron transfer
Enzyme models
Iron oxo complexes

Access to Document

10.1002/anie.200904427

Cite this

@article{d1a37a231cf547008a3d9acd7867f10f,

title = "Electron-transfer properties of an efficient nonheme iron oxidation catalyst with a tetradentate bispidine ligand",

abstract = "(Graph Presentation) The oxidation catalyst [ (L) FeIV=O] (see picture; L is a tetradentate bispidine ligand) has the highest known one-electron reduction potential for a FeIV=O species (0.73 V vs. SCE). Investigations into the electron-transfer kinetics show a linear correlation with the bond dissociation energy of the organic substrates.",

keywords = "Bioinorganic chemistry, C-H activation, Electron transfer, Enzyme models, Iron oxo complexes",

author = "Peter Comba and Shunichi Fukuzumi and Hiroaki Kotani and Steffen Wunderlich",

year = "2010",

month = mar,

day = "29",

doi = "10.1002/anie.200904427",

language = "English",

volume = "49",

pages = "2622--2625",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "14",

}

TY - JOUR

T1 - Electron-transfer properties of an efficient nonheme iron oxidation catalyst with a tetradentate bispidine ligand

AU - Comba, Peter

AU - Fukuzumi, Shunichi

AU - Kotani, Hiroaki

AU - Wunderlich, Steffen

PY - 2010/3/29

Y1 - 2010/3/29

N2 - (Graph Presentation) The oxidation catalyst [ (L) FeIV=O] (see picture; L is a tetradentate bispidine ligand) has the highest known one-electron reduction potential for a FeIV=O species (0.73 V vs. SCE). Investigations into the electron-transfer kinetics show a linear correlation with the bond dissociation energy of the organic substrates.

AB - (Graph Presentation) The oxidation catalyst [ (L) FeIV=O] (see picture; L is a tetradentate bispidine ligand) has the highest known one-electron reduction potential for a FeIV=O species (0.73 V vs. SCE). Investigations into the electron-transfer kinetics show a linear correlation with the bond dissociation energy of the organic substrates.

KW - Bioinorganic chemistry

KW - C-H activation

KW - Electron transfer

KW - Enzyme models

KW - Iron oxo complexes

UR - https://www.scopus.com/pages/publications/77950217350

U2 - 10.1002/anie.200904427

DO - 10.1002/anie.200904427

M3 - Article

C2 - 20229541

AN - SCOPUS:77950217350

SN - 1433-7851

VL - 49

SP - 2622

EP - 2625

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 14

ER -

Electron-transfer properties of an efficient nonheme iron oxidation catalyst with a tetradentate bispidine ligand

Abstract

Keywords

Access to Document

Fingerprint

Cite this