Abstract
(Graph Presentation) The oxidation catalyst [ (L) FeIV=O] (see picture; L is a tetradentate bispidine ligand) has the highest known one-electron reduction potential for a FeIV=O species (0.73 V vs. SCE). Investigations into the electron-transfer kinetics show a linear correlation with the bond dissociation energy of the organic substrates.
Original language | English |
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Pages (from-to) | 2622-2625 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 49 |
Issue number | 14 |
DOIs | |
State | Published - 29 Mar 2010 |
Keywords
- Bioinorganic chemistry
- C-H activation
- Electron transfer
- Enzyme models
- Iron oxo complexes