Electron-transfer properties of a nonheme manganese(IV)–oxo complex acting as a stronger one-electron oxidant than the iron(IV)–oxo analogue

Heejung Yoon, Yuma Morimoto, Yong Min Lee, Wonwoo Nam, Shunichi Fukuzumi

Research output: Contribution to journalArticlepeer-review

30 Scopus citations

Abstract

Electron-transfer properties of a nonheme Mn(IV)–oxo complex, [(Bn-TPEN)MnIV(O)]2+, reveals that Mn(IV)–oxo complex acts as a stronger one-electron oxidant than the Fe(IV)–oxo analogue. As a result, an electron transfer process in N-dealkylation has been detected by a transient radical cation intermediate, para-Me-DMA-+, in the oxidation of para-Me-DMA by [(Bn-TPEN)MnIV(O)]2+.

Original languageEnglish
Pages (from-to)11187-11189
Number of pages3
JournalChemical Communications
Volume48
Issue number91
DOIs
StatePublished - 22 Oct 2012

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