Electron-spectroscopy study of Charge transfer and dimer formation

J. Schnadt, P. Brühwiler, N. Mårtensson, A. Lassesson, F. Rohmund, E. Campbell

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

(Formula presented) compounds (Formula presented) were studied for average Li concentration (Formula presented) using photoelectron spectroscopy. Strong evidence is found for the formation of (Formula presented) dimers, as well as a second phase. The study suggests that the smallest alkali-metal Li bonds to (Formula presented) largely ionically for certain configurations. An investigation of the Li (Formula presented) level shows that under certain conditions the energetics favor a backdonation of the transferred electron to the Li ion.

Original languageEnglish
Pages (from-to)4253-4256
Number of pages4
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume62
Issue number7
DOIs
StatePublished - 2000

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