Electro-optic response of an electrostatically self-assembled single polymeric monolayer in attenuated total reflection configuration

H. J. Chang; N. Y. Ha; Ahyoung Kim; Byoungchoo Park; Jung Hyurk Lim; Eun Jin Park; Jae Ho Kim; Suck Hyun Lee; J. W. Wu

doi:10.1016/j.optcom.2004.06.024

Electro-optic response of an electrostatically self-assembled single polymeric monolayer in attenuated total reflection configuration

H. J. Chang
, N. Y. Ha
, Ahyoung Kim
, Byoungchoo Park
, Jung Hyurk Lim
, Eun Jin Park
, Jae Ho Kim
, Suck Hyun Lee
, J. W. Wu

Department of Physics

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

An electrostatically self-assembled monolayer, composed of a pair of layers of anionic molecules and cationic polymers with a hemicyanine pendent group, was fabricated onto a thin silver film. By use of the attenuated total internal reflection technique, surface plasmon resonance and reflection modulation spectra were measured to determine the electro-optic coefficients of the monolayer. In order to take into account the dielectric property of each layer, a five-layer model is adopted in obtaining the electro-optic coefficients. From the temperature dependence measurement of reflection modulation signal, the hyperpolarizabilities of the hemicyanine pendent chromophore in benzenoid and quinoid forms are obtained.

Original language	English
Pages (from-to)	29-38
Number of pages	10
Journal	Optics Communications
Volume	240
Issue number	1-3
DOIs	https://doi.org/10.1016/j.optcom.2004.06.024
State	Published - 1 Oct 2004

Bibliographical note

Funding Information:
This work was supported by the Korea Science and Engineering Foundation through the Quantum Photonic Science Research Center at Hanyang University.

Keywords

Electro-optic effect
Self-assembled monolayer

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10.1016/j.optcom.2004.06.024

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title = "Electro-optic response of an electrostatically self-assembled single polymeric monolayer in attenuated total reflection configuration",

abstract = "An electrostatically self-assembled monolayer, composed of a pair of layers of anionic molecules and cationic polymers with a hemicyanine pendent group, was fabricated onto a thin silver film. By use of the attenuated total internal reflection technique, surface plasmon resonance and reflection modulation spectra were measured to determine the electro-optic coefficients of the monolayer. In order to take into account the dielectric property of each layer, a five-layer model is adopted in obtaining the electro-optic coefficients. From the temperature dependence measurement of reflection modulation signal, the hyperpolarizabilities of the hemicyanine pendent chromophore in benzenoid and quinoid forms are obtained.",

keywords = "Electro-optic effect, Self-assembled monolayer",

author = "Chang, \{H. J.\} and Ha, \{N. Y.\} and Ahyoung Kim and Byoungchoo Park and Lim, \{Jung Hyurk\} and Park, \{Eun Jin\} and Kim, \{Jae Ho\} and Lee, \{Suck Hyun\} and Wu, \{J. W.\}",

note = "Funding Information: This work was supported by the Korea Science and Engineering Foundation through the Quantum Photonic Science Research Center at Hanyang University.",

year = "2004",

month = oct,

day = "1",

doi = "10.1016/j.optcom.2004.06.024",

language = "English",

volume = "240",

pages = "29--38",

journal = "Optics Communications",

issn = "0030-4018",

publisher = "Elsevier B.V.",

number = "1-3",

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TY - JOUR

T1 - Electro-optic response of an electrostatically self-assembled single polymeric monolayer in attenuated total reflection configuration

AU - Chang, H. J.

AU - Ha, N. Y.

AU - Kim, Ahyoung

AU - Park, Byoungchoo

AU - Lim, Jung Hyurk

AU - Park, Eun Jin

AU - Kim, Jae Ho

AU - Lee, Suck Hyun

AU - Wu, J. W.

N1 - Funding Information: This work was supported by the Korea Science and Engineering Foundation through the Quantum Photonic Science Research Center at Hanyang University.

PY - 2004/10/1

Y1 - 2004/10/1

N2 - An electrostatically self-assembled monolayer, composed of a pair of layers of anionic molecules and cationic polymers with a hemicyanine pendent group, was fabricated onto a thin silver film. By use of the attenuated total internal reflection technique, surface plasmon resonance and reflection modulation spectra were measured to determine the electro-optic coefficients of the monolayer. In order to take into account the dielectric property of each layer, a five-layer model is adopted in obtaining the electro-optic coefficients. From the temperature dependence measurement of reflection modulation signal, the hyperpolarizabilities of the hemicyanine pendent chromophore in benzenoid and quinoid forms are obtained.

AB - An electrostatically self-assembled monolayer, composed of a pair of layers of anionic molecules and cationic polymers with a hemicyanine pendent group, was fabricated onto a thin silver film. By use of the attenuated total internal reflection technique, surface plasmon resonance and reflection modulation spectra were measured to determine the electro-optic coefficients of the monolayer. In order to take into account the dielectric property of each layer, a five-layer model is adopted in obtaining the electro-optic coefficients. From the temperature dependence measurement of reflection modulation signal, the hyperpolarizabilities of the hemicyanine pendent chromophore in benzenoid and quinoid forms are obtained.

KW - Electro-optic effect

KW - Self-assembled monolayer

UR - https://www.scopus.com/pages/publications/4444335421

U2 - 10.1016/j.optcom.2004.06.024

DO - 10.1016/j.optcom.2004.06.024

M3 - Article

AN - SCOPUS:4444335421

SN - 0030-4018

VL - 240

SP - 29

EP - 38

JO - Optics Communications

JF - Optics Communications

IS - 1-3

ER -

Electro-optic response of an electrostatically self-assembled single polymeric monolayer in attenuated total reflection configuration

Abstract

Bibliographical note

Keywords

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