Electro-optic response of an electrostatically self-assembled single polymeric monolayer in attenuated total reflection configuration

H. J. Chang; N. Y. Ha; Ahyoung Kim; Byoungchoo Park; Jung Hyurk Lim; Eun Jin Park; Jae Ho Kim; Suck Hyun Lee; J. W. Wu

doi:10.1016/j.optcom.2004.06.024

Electro-optic response of an electrostatically self-assembled single polymeric monolayer in attenuated total reflection configuration

H. J. Chang, N. Y. Ha, Ahyoung Kim, Byoungchoo Park, Jung Hyurk Lim, Eun Jin Park, Jae Ho Kim, Suck Hyun Lee, J. W. Wu

Department of Physics

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

An electrostatically self-assembled monolayer, composed of a pair of layers of anionic molecules and cationic polymers with a hemicyanine pendent group, was fabricated onto a thin silver film. By use of the attenuated total internal reflection technique, surface plasmon resonance and reflection modulation spectra were measured to determine the electro-optic coefficients of the monolayer. In order to take into account the dielectric property of each layer, a five-layer model is adopted in obtaining the electro-optic coefficients. From the temperature dependence measurement of reflection modulation signal, the hyperpolarizabilities of the hemicyanine pendent chromophore in benzenoid and quinoid forms are obtained.

Original language	English
Pages (from-to)	29-38
Number of pages	10
Journal	Optics Communications
Volume	240
Issue number	1-3
DOIs	https://doi.org/10.1016/j.optcom.2004.06.024
State	Published - 1 Oct 2004

Bibliographical note

Funding Information:
This work was supported by the Korea Science and Engineering Foundation through the Quantum Photonic Science Research Center at Hanyang University.

Keywords

Electro-optic effect
Self-assembled monolayer

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10.1016/j.optcom.2004.06.024

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title = "Electro-optic response of an electrostatically self-assembled single polymeric monolayer in attenuated total reflection configuration",

abstract = "An electrostatically self-assembled monolayer, composed of a pair of layers of anionic molecules and cationic polymers with a hemicyanine pendent group, was fabricated onto a thin silver film. By use of the attenuated total internal reflection technique, surface plasmon resonance and reflection modulation spectra were measured to determine the electro-optic coefficients of the monolayer. In order to take into account the dielectric property of each layer, a five-layer model is adopted in obtaining the electro-optic coefficients. From the temperature dependence measurement of reflection modulation signal, the hyperpolarizabilities of the hemicyanine pendent chromophore in benzenoid and quinoid forms are obtained.",

keywords = "Electro-optic effect, Self-assembled monolayer",

author = "Chang, {H. J.} and Ha, {N. Y.} and Ahyoung Kim and Byoungchoo Park and Lim, {Jung Hyurk} and Park, {Eun Jin} and Kim, {Jae Ho} and Lee, {Suck Hyun} and Wu, {J. W.}",

note = "Funding Information: This work was supported by the Korea Science and Engineering Foundation through the Quantum Photonic Science Research Center at Hanyang University.",

year = "2004",

month = oct,

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doi = "10.1016/j.optcom.2004.06.024",

language = "English",

volume = "240",

pages = "29--38",

journal = "Optics Communications",

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T1 - Electro-optic response of an electrostatically self-assembled single polymeric monolayer in attenuated total reflection configuration

AU - Chang, H. J.

AU - Ha, N. Y.

AU - Kim, Ahyoung

AU - Park, Byoungchoo

AU - Lim, Jung Hyurk

AU - Park, Eun Jin

AU - Kim, Jae Ho

AU - Lee, Suck Hyun

AU - Wu, J. W.

N1 - Funding Information: This work was supported by the Korea Science and Engineering Foundation through the Quantum Photonic Science Research Center at Hanyang University.

PY - 2004/10/1

Y1 - 2004/10/1

N2 - An electrostatically self-assembled monolayer, composed of a pair of layers of anionic molecules and cationic polymers with a hemicyanine pendent group, was fabricated onto a thin silver film. By use of the attenuated total internal reflection technique, surface plasmon resonance and reflection modulation spectra were measured to determine the electro-optic coefficients of the monolayer. In order to take into account the dielectric property of each layer, a five-layer model is adopted in obtaining the electro-optic coefficients. From the temperature dependence measurement of reflection modulation signal, the hyperpolarizabilities of the hemicyanine pendent chromophore in benzenoid and quinoid forms are obtained.

AB - An electrostatically self-assembled monolayer, composed of a pair of layers of anionic molecules and cationic polymers with a hemicyanine pendent group, was fabricated onto a thin silver film. By use of the attenuated total internal reflection technique, surface plasmon resonance and reflection modulation spectra were measured to determine the electro-optic coefficients of the monolayer. In order to take into account the dielectric property of each layer, a five-layer model is adopted in obtaining the electro-optic coefficients. From the temperature dependence measurement of reflection modulation signal, the hyperpolarizabilities of the hemicyanine pendent chromophore in benzenoid and quinoid forms are obtained.

KW - Electro-optic effect

KW - Self-assembled monolayer

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DO - 10.1016/j.optcom.2004.06.024

M3 - Article

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SN - 0030-4018

VL - 240

SP - 29

EP - 38

JO - Optics Communications

JF - Optics Communications

IS - 1-3

ER -

Electro-optic response of an electrostatically self-assembled single polymeric monolayer in attenuated total reflection configuration

Abstract

Bibliographical note

Keywords

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