Effect of anion binding on charge stabilization in a bis-fullerene- oxoporphyrinogen conjugate

Jonathan P. Hill; Mohamed E. El-Khouly; Richard Charvet; Navaneetha K. Subbaiyan; Katsuhiko Ariga; Shunichi Fukuzumi; Francis D'Souza

doi:10.1039/c0cc03167d

Effect of anion binding on charge stabilization in a bis-fullerene- oxoporphyrinogen conjugate

Jonathan P. Hill, Mohamed E. El-Khouly, Richard Charvet, Navaneetha K. Subbaiyan, Katsuhiko Ariga, Shunichi Fukuzumi, Francis D'Souza

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Presence of strongly binding anion, F^- stabilizes the photo-induced charge-separated states of a bis-fullerene-substituted oxoporphyrinogen due to the large shift in the oxidation potential of the oxoporphyrinogen moiety upon anion binding through hydrogen bonding at its core.

Original language	English
Pages (from-to)	7933-7935
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	42
DOIs	https://doi.org/10.1039/c0cc03167d
State	Published - 14 Nov 2010

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title = "Effect of anion binding on charge stabilization in a bis-fullerene- oxoporphyrinogen conjugate",

abstract = "Presence of strongly binding anion, F- stabilizes the photo-induced charge-separated states of a bis-fullerene-substituted oxoporphyrinogen due to the large shift in the oxidation potential of the oxoporphyrinogen moiety upon anion binding through hydrogen bonding at its core.",

author = "Hill, {Jonathan P.} and El-Khouly, {Mohamed E.} and Richard Charvet and Subbaiyan, {Navaneetha K.} and Katsuhiko Ariga and Shunichi Fukuzumi and Francis D'Souza",

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T1 - Effect of anion binding on charge stabilization in a bis-fullerene- oxoporphyrinogen conjugate

AU - Hill, Jonathan P.

AU - El-Khouly, Mohamed E.

AU - Charvet, Richard

AU - Subbaiyan, Navaneetha K.

AU - Ariga, Katsuhiko

AU - Fukuzumi, Shunichi

AU - D'Souza, Francis

PY - 2010/11/14

Y1 - 2010/11/14

N2 - Presence of strongly binding anion, F- stabilizes the photo-induced charge-separated states of a bis-fullerene-substituted oxoporphyrinogen due to the large shift in the oxidation potential of the oxoporphyrinogen moiety upon anion binding through hydrogen bonding at its core.

AB - Presence of strongly binding anion, F- stabilizes the photo-induced charge-separated states of a bis-fullerene-substituted oxoporphyrinogen due to the large shift in the oxidation potential of the oxoporphyrinogen moiety upon anion binding through hydrogen bonding at its core.

UR - http://www.scopus.com/inward/record.url?scp=77958451232&partnerID=8YFLogxK

U2 - 10.1039/c0cc03167d

DO - 10.1039/c0cc03167d

M3 - Article

C2 - 20862426

AN - SCOPUS:77958451232

SN - 1359-7345

VL - 46

SP - 7933

EP - 7935

JO - Chemical Communications

JF - Chemical Communications

IS - 42

ER -

Effect of anion binding on charge stabilization in a bis-fullerene- oxoporphyrinogen conjugate

Abstract

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