Dual function photocatalysis of cyano-bridged heteronuclear metal complexes for water oxidation and two-electron reduction of dioxygen to produce hydrogen peroxide as a solar fuel

Yusuke Aratani; Tomoyoshi Suenobu; Kei Ohkubo; Yusuke Yamada; Shunichi Fukuzumi

doi:10.1039/C7CC00621G

Dual function photocatalysis of cyano-bridged heteronuclear metal complexes for water oxidation and two-electron reduction of dioxygen to produce hydrogen peroxide as a solar fuel

Yusuke Aratani
, Tomoyoshi Suenobu
, Kei Ohkubo
, Yusuke Yamada
, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

The photocatalytic production of hydrogen peroxide from water and dioxygen under visible light irradiation was made possible by using polymeric cyano-bridged heteronuclear metal complexes (M^II[Ru^II(CN)₄(bpy)]; M^II = Ni^II, Fe^II and Mn^II), where the photocatalytic two-electron reduction of O₂ and water oxidation were catalysed by the Ru and M^II moieties, respectively.

Original language	English
Pages (from-to)	3473-3476
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	24
DOIs	https://doi.org/10.1039/C7CC00621G
State	Published - 2017

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© The Royal Society of Chemistry.

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title = "Dual function photocatalysis of cyano-bridged heteronuclear metal complexes for water oxidation and two-electron reduction of dioxygen to produce hydrogen peroxide as a solar fuel",

abstract = "The photocatalytic production of hydrogen peroxide from water and dioxygen under visible light irradiation was made possible by using polymeric cyano-bridged heteronuclear metal complexes (MII[RuII(CN)4(bpy)]; MII = NiII, FeII and MnII), where the photocatalytic two-electron reduction of O2 and water oxidation were catalysed by the Ru and MII moieties, respectively.",

author = "Yusuke Aratani and Tomoyoshi Suenobu and Kei Ohkubo and Yusuke Yamada and Shunichi Fukuzumi",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/C7CC00621G",

language = "English",

volume = "53",

pages = "3473--3476",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "24",

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Dual function photocatalysis of cyano-bridged heteronuclear metal complexes for water oxidation and two-electron reduction of dioxygen to produce hydrogen peroxide as a solar fuel. / Aratani, Yusuke; Suenobu, Tomoyoshi; Ohkubo, Kei et al.
In: Chemical Communications, Vol. 53, No. 24, 2017, p. 3473-3476.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Dual function photocatalysis of cyano-bridged heteronuclear metal complexes for water oxidation and two-electron reduction of dioxygen to produce hydrogen peroxide as a solar fuel

AU - Aratani, Yusuke

AU - Suenobu, Tomoyoshi

AU - Ohkubo, Kei

AU - Yamada, Yusuke

AU - Fukuzumi, Shunichi

PY - 2017

Y1 - 2017

N2 - The photocatalytic production of hydrogen peroxide from water and dioxygen under visible light irradiation was made possible by using polymeric cyano-bridged heteronuclear metal complexes (MII[RuII(CN)4(bpy)]; MII = NiII, FeII and MnII), where the photocatalytic two-electron reduction of O2 and water oxidation were catalysed by the Ru and MII moieties, respectively.

AB - The photocatalytic production of hydrogen peroxide from water and dioxygen under visible light irradiation was made possible by using polymeric cyano-bridged heteronuclear metal complexes (MII[RuII(CN)4(bpy)]; MII = NiII, FeII and MnII), where the photocatalytic two-electron reduction of O2 and water oxidation were catalysed by the Ru and MII moieties, respectively.

UR - https://www.scopus.com/pages/publications/85016010596

U2 - 10.1039/C7CC00621G

DO - 10.1039/C7CC00621G

M3 - Article

C2 - 28271095

AN - SCOPUS:85016010596

SN - 1359-7345

VL - 53

SP - 3473

EP - 3476

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

Dual function photocatalysis of cyano-bridged heteronuclear metal complexes for water oxidation and two-electron reduction of dioxygen to produce hydrogen peroxide as a solar fuel

Abstract

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