Dramatic enhancement of catalytic activity in an ionic liquid: Highly practical Friedel-Crafts alkenylation of arenes with alkynes catalyzed by metal triflates

Choong Eui Song; Da Un Jung; Su Yhen Choung; Eun Joo Roh; Sang Gi Lee

doi:10.1002/anie.200460292

Dramatic enhancement of catalytic activity in an ionic liquid: Highly practical Friedel-Crafts alkenylation of arenes with alkynes catalyzed by metal triflates

Choong Eui Song
, Da Un Jung
, Su Yhen Choung
, Eun Joo Roh
, Sang Gi Lee

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

188 Scopus citations

Abstract

A simple and highly efficient method for the Friedel-Crafts alkenylation of aromatic compounds has been developed by using a metal triflate (OTf) catalyst in an ionic liquid (see scheme, bmim = 1-butyl-3-methylimidazolium). Not only is the catalytic activity significantly enhanced in the ionic liquid and by-product formation decreased, but some reactions that were not possible in conventional organic solvents were shown to proceed smoothly.

Original language	English
Pages (from-to)	6183-6185
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	45
DOIs	https://doi.org/10.1002/anie.200460292
State	Published - 19 Nov 2004

Keywords

Alkenylation
C-C bond formation
Homogeneous catalysis
Ionic liquids
Lewis acids

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10.1002/anie.200460292

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title = "Dramatic enhancement of catalytic activity in an ionic liquid: Highly practical Friedel-Crafts alkenylation of arenes with alkynes catalyzed by metal triflates",

abstract = "A simple and highly efficient method for the Friedel-Crafts alkenylation of aromatic compounds has been developed by using a metal triflate (OTf) catalyst in an ionic liquid (see scheme, bmim = 1-butyl-3-methylimidazolium). Not only is the catalytic activity significantly enhanced in the ionic liquid and by-product formation decreased, but some reactions that were not possible in conventional organic solvents were shown to proceed smoothly.",

keywords = "Alkenylation, C-C bond formation, Homogeneous catalysis, Ionic liquids, Lewis acids",

author = "Song, \{Choong Eui\} and Jung, \{Da Un\} and Choung, \{Su Yhen\} and Roh, \{Eun Joo\} and Lee, \{Sang Gi\}",

year = "2004",

month = nov,

day = "19",

doi = "10.1002/anie.200460292",

language = "English",

volume = "43",

pages = "6183--6185",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "45",

}

Dramatic enhancement of catalytic activity in an ionic liquid: Highly practical Friedel-Crafts alkenylation of arenes with alkynes catalyzed by metal triflates. / Song, Choong Eui; Jung, Da Un; Choung, Su Yhen et al.
In: Angewandte Chemie - International Edition, Vol. 43, No. 45, 19.11.2004, p. 6183-6185.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Dramatic enhancement of catalytic activity in an ionic liquid

T2 - Highly practical Friedel-Crafts alkenylation of arenes with alkynes catalyzed by metal triflates

AU - Song, Choong Eui

AU - Jung, Da Un

AU - Choung, Su Yhen

AU - Roh, Eun Joo

AU - Lee, Sang Gi

PY - 2004/11/19

Y1 - 2004/11/19

N2 - A simple and highly efficient method for the Friedel-Crafts alkenylation of aromatic compounds has been developed by using a metal triflate (OTf) catalyst in an ionic liquid (see scheme, bmim = 1-butyl-3-methylimidazolium). Not only is the catalytic activity significantly enhanced in the ionic liquid and by-product formation decreased, but some reactions that were not possible in conventional organic solvents were shown to proceed smoothly.

AB - A simple and highly efficient method for the Friedel-Crafts alkenylation of aromatic compounds has been developed by using a metal triflate (OTf) catalyst in an ionic liquid (see scheme, bmim = 1-butyl-3-methylimidazolium). Not only is the catalytic activity significantly enhanced in the ionic liquid and by-product formation decreased, but some reactions that were not possible in conventional organic solvents were shown to proceed smoothly.

KW - Alkenylation

KW - C-C bond formation

KW - Homogeneous catalysis

KW - Ionic liquids

KW - Lewis acids

UR - https://www.scopus.com/pages/publications/10044248730

U2 - 10.1002/anie.200460292

DO - 10.1002/anie.200460292

M3 - Article

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AN - SCOPUS:10044248730

SN - 1433-7851

VL - 43

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EP - 6185

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 45

ER -

Dramatic enhancement of catalytic activity in an ionic liquid: Highly practical Friedel-Crafts alkenylation of arenes with alkynes catalyzed by metal triflates

Abstract

Keywords

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