Dodecanuclear rhenium cluster complexes with an interstitial carbon atom: Synthesis, structures and properties of two new compounds K6[Re 12CS17(OH)6]·4H2O and Na 12Re12CS17(SO3)6· 48.5H2O

Yuri V. Mironov; Svetlana G. Kozlova; Sung Jin Kim; William S. Sheldrick; Vladimir E. Fedorov

doi:10.1016/j.poly.2010.09.010

Dodecanuclear rhenium cluster complexes with an interstitial carbon atom: Synthesis, structures and properties of two new compounds K₆[Re ₁₂CS₁₇(OH)₆]·4H₂O and Na ₁₂Re₁₂CS₁₇(SO₃)₆· 48.5H₂O

Yuri V. Mironov, Svetlana G. Kozlova, Sung Jin Kim, William S. Sheldrick, Vladimir E. Fedorov

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The dodecanuclear rhenium anionic complex with terminal hydroxo ligands [Re₁₂CS₁₇(OH)₆]^6- was obtained by the reaction of K₆[Re₁₂CS₁₇(CN) ₆]·20H₂O with molten KOH at 300 °C. The cluster complex was crystallized as a potassium salt from aqueous solution. The reaction between K₆[Re₁₂CS₁₇(OH) ₆]·4H₂O and Na₂S₂O ₄ in water under reflux results in the formation of the complex Na₁₂[Re₁₂CS₁₇(SO₃) ₆]·48.5H₂O. Both new compounds were characterized by single-crystal X-ray diffraction, elemental analyses and IR spectroscopy. The electronic structure of [Re₁₂CS₁₇(OH)₆] ^6- was also elucidated by DFT calculations.

Original language	English
Pages (from-to)	3283-3286
Number of pages	4
Journal	Polyhedron
Volume	29
Issue number	18
DOIs	https://doi.org/10.1016/j.poly.2010.09.010
State	Published - 7 Dec 2010

Bibliographical note

Funding Information:
This work was supported by the Russian Foundation for Basic Research (Grants 10-03-01040 , 08-03-00267 , 08-03-00826 ) and the SRC of the Korea Science and Engineering Foundation (Grant R11-2005-008-0000-0 ). Y.V. Mironov also thanks the AvH foundation.

Keywords

Crystal structure
Dodecanuclear cluster complexes
Electronic structure
Rhenium
Synthesis

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10.1016/j.poly.2010.09.010

Cite this

@article{a6d8caeac3894f258787cf472284e6ca,

title = "Dodecanuclear rhenium cluster complexes with an interstitial carbon atom: Synthesis, structures and properties of two new compounds K6[Re 12CS17(OH)6]·4H2O and Na 12Re12CS17(SO3)6· 48.5H2O",

abstract = "The dodecanuclear rhenium anionic complex with terminal hydroxo ligands [Re12CS17(OH)6]6- was obtained by the reaction of K6[Re12CS17(CN) 6]·20H2O with molten KOH at 300 °C. The cluster complex was crystallized as a potassium salt from aqueous solution. The reaction between K6[Re12CS17(OH) 6]·4H2O and Na2S2O 4 in water under reflux results in the formation of the complex Na12[Re12CS17(SO3) 6]·48.5H2O. Both new compounds were characterized by single-crystal X-ray diffraction, elemental analyses and IR spectroscopy. The electronic structure of [Re12CS17(OH)6] 6- was also elucidated by DFT calculations.",

keywords = "Crystal structure, Dodecanuclear cluster complexes, Electronic structure, Rhenium, Synthesis",

author = "Mironov, {Yuri V.} and Kozlova, {Svetlana G.} and Kim, {Sung Jin} and Sheldrick, {William S.} and Fedorov, {Vladimir E.}",

note = "Funding Information: This work was supported by the Russian Foundation for Basic Research (Grants 10-03-01040 , 08-03-00267 , 08-03-00826 ) and the SRC of the Korea Science and Engineering Foundation (Grant R11-2005-008-0000-0 ). Y.V. Mironov also thanks the AvH foundation. ",

year = "2010",

month = dec,

day = "7",

doi = "10.1016/j.poly.2010.09.010",

language = "English",

volume = "29",

pages = "3283--3286",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "18",

}

Dodecanuclear rhenium cluster complexes with an interstitial carbon atom: Synthesis, structures and properties of two new compounds K₆[Re ₁₂CS₁₇(OH)₆]·4H₂O and Na ₁₂Re₁₂CS₁₇(SO₃)₆· 48.5H₂O. / Mironov, Yuri V.; Kozlova, Svetlana G.; Kim, Sung Jin et al.
In: Polyhedron, Vol. 29, No. 18, 07.12.2010, p. 3283-3286.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Dodecanuclear rhenium cluster complexes with an interstitial carbon atom

T2 - Synthesis, structures and properties of two new compounds K6[Re 12CS17(OH)6]·4H2O and Na 12Re12CS17(SO3)6· 48.5H2O

AU - Mironov, Yuri V.

AU - Kozlova, Svetlana G.

AU - Kim, Sung Jin

AU - Sheldrick, William S.

AU - Fedorov, Vladimir E.

N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research (Grants 10-03-01040 , 08-03-00267 , 08-03-00826 ) and the SRC of the Korea Science and Engineering Foundation (Grant R11-2005-008-0000-0 ). Y.V. Mironov also thanks the AvH foundation.

PY - 2010/12/7

Y1 - 2010/12/7

N2 - The dodecanuclear rhenium anionic complex with terminal hydroxo ligands [Re12CS17(OH)6]6- was obtained by the reaction of K6[Re12CS17(CN) 6]·20H2O with molten KOH at 300 °C. The cluster complex was crystallized as a potassium salt from aqueous solution. The reaction between K6[Re12CS17(OH) 6]·4H2O and Na2S2O 4 in water under reflux results in the formation of the complex Na12[Re12CS17(SO3) 6]·48.5H2O. Both new compounds were characterized by single-crystal X-ray diffraction, elemental analyses and IR spectroscopy. The electronic structure of [Re12CS17(OH)6] 6- was also elucidated by DFT calculations.

AB - The dodecanuclear rhenium anionic complex with terminal hydroxo ligands [Re12CS17(OH)6]6- was obtained by the reaction of K6[Re12CS17(CN) 6]·20H2O with molten KOH at 300 °C. The cluster complex was crystallized as a potassium salt from aqueous solution. The reaction between K6[Re12CS17(OH) 6]·4H2O and Na2S2O 4 in water under reflux results in the formation of the complex Na12[Re12CS17(SO3) 6]·48.5H2O. Both new compounds were characterized by single-crystal X-ray diffraction, elemental analyses and IR spectroscopy. The electronic structure of [Re12CS17(OH)6] 6- was also elucidated by DFT calculations.

KW - Crystal structure

KW - Dodecanuclear cluster complexes

KW - Electronic structure

KW - Rhenium

KW - Synthesis

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JF - Polyhedron

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