Direct synthesis of hydrogen peroxide from hydrogen and oxygen by using a water-soluble iridium complex and flavin mononucleotide

Satoshi Shibata; Tomoyoshi Suenobu; Shunichi Fukuzumi

doi:10.1002/anie.201307273

Direct synthesis of hydrogen peroxide from hydrogen and oxygen by using a water-soluble iridium complex and flavin mononucleotide

Satoshi Shibata, Tomoyoshi Suenobu, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

H₂, O₂ to H₂O₂: The direct synthesis of hydrogen peroxide from hydrogen and oxygen in water has been made possible by using an iridium(III) complex, [Ir^III(Cp)(4-(1H-pyrazol- 1-yl-κN²)benzoic acid-κC³)(H ₂O)]₂SO₄, and flavin mononucleotide. This method gives hydrogen peroxide with a high turnover number (847) and yield (19.2 %) under normal pressure and at room temperature.

Original language	English
Pages (from-to)	12327-12331
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	47
DOIs	https://doi.org/10.1002/anie.201307273
State	Published - 18 Nov 2013

Keywords

homogeneous catalysis
hydrogen
hydrogen peroxide
iridium
oxygen

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title = "Direct synthesis of hydrogen peroxide from hydrogen and oxygen by using a water-soluble iridium complex and flavin mononucleotide",

abstract = "H2, O2 to H2O2: The direct synthesis of hydrogen peroxide from hydrogen and oxygen in water has been made possible by using an iridium(III) complex, [IrIII(Cp)(4-(1H-pyrazol- 1-yl-κN2)benzoic acid-κC3)(H 2O)]2SO4, and flavin mononucleotide. This method gives hydrogen peroxide with a high turnover number (847) and yield (19.2 %) under normal pressure and at room temperature.",

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author = "Satoshi Shibata and Tomoyoshi Suenobu and Shunichi Fukuzumi",

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T1 - Direct synthesis of hydrogen peroxide from hydrogen and oxygen by using a water-soluble iridium complex and flavin mononucleotide

AU - Shibata, Satoshi

AU - Suenobu, Tomoyoshi

AU - Fukuzumi, Shunichi

PY - 2013/11/18

Y1 - 2013/11/18

N2 - H2, O2 to H2O2: The direct synthesis of hydrogen peroxide from hydrogen and oxygen in water has been made possible by using an iridium(III) complex, [IrIII(Cp)(4-(1H-pyrazol- 1-yl-κN2)benzoic acid-κC3)(H 2O)]2SO4, and flavin mononucleotide. This method gives hydrogen peroxide with a high turnover number (847) and yield (19.2 %) under normal pressure and at room temperature.

AB - H2, O2 to H2O2: The direct synthesis of hydrogen peroxide from hydrogen and oxygen in water has been made possible by using an iridium(III) complex, [IrIII(Cp)(4-(1H-pyrazol- 1-yl-κN2)benzoic acid-κC3)(H 2O)]2SO4, and flavin mononucleotide. This method gives hydrogen peroxide with a high turnover number (847) and yield (19.2 %) under normal pressure and at room temperature.

KW - homogeneous catalysis

KW - hydrogen

KW - hydrogen peroxide

KW - iridium

KW - oxygen

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DO - 10.1002/anie.201307273

M3 - Article

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SN - 1433-7851

VL - 52

SP - 12327

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 47

ER -

Direct synthesis of hydrogen peroxide from hydrogen and oxygen by using a water-soluble iridium complex and flavin mononucleotide

Abstract

Keywords

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