@article{b48f3267d32c468caaa40e4ec9f8fff3,
title = "Direct oxygen atom transfer versus electron transfer mechanisms in the phosphine oxidation by nonheme Mn(IV)-oxo complexes",
abstract = "Direct oxygen atom transfer from a nonheme Mn(iv)-oxo complex, [(Bn-TPEN)MnIV(O)]2+, to triphenylphosphine (Ph3P) derivatives occurs with a significant steric effect resulting from the ortho-substituents on the phenyl group of the Ph3P derivatives, whereas the phosphine oxygenation by a Mn(iv)-oxo complex in the presence of HOTf occurs via an electron transfer mechanism without the substrate-steric effect.",
author = "Lee, {Yong Min} and Mi Yoo and Heejung Yoon and Li, {Xiao Xi} and Wonwoo Nam and Shunichi Fukuzumi",
note = "Funding Information: This work was gratefully supported by the NRF of Korea through CRI (NRF-2012R1A3A2048842 to W. N.), GRL (NRF-2010-00353 to W. N.) and the Basic Science Research Program (2017R1D1A1B03029982 to Y. M. L. and 2017R1D1A1B03032615 to S. F.), and by a Grant-in-Aid (no. 16H02268 to S. F.) from the Ministry of Education, Culture, Sports, Science and Technology (MEXT) and a SENTAN project (to S. F.) from Japan Science and Technology Agency, Japan. Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",
year = "2017",
doi = "10.1039/c7cc04035k",
language = "English",
volume = "53",
pages = "9352--9355",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "67",
}