Direct evidence for an iron(IV)-oxo porphyrin π-cation radical as an active oxidant in catalytic oxygenation reactions

Ah Rim Han; Yu Jin Jeong; Yaeun Kang; Jung Yoon Lee; Mi Sook Seo; Wonwoo Nam

doi:10.1039/b716558g

Direct evidence for an iron(IV)-oxo porphyrin π-cation radical as an active oxidant in catalytic oxygenation reactions

Ah Rim Han, Yu Jin Jeong, Yaeun Kang, Jung Yoon Lee, Mi Sook Seo, Wonwoo Nam

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

A high-valent iron(iv)-oxo porphyrin π-cation radical is an active oxidant in the catalytic oxygenation of organic substrates by an iron(iii) porphyrin complex and peracids, whereas an iron(iii)-oxidant porphyrin adduct is a sluggish oxidant in iron porphyrin model reactions.

Original language	English
Pages (from-to)	1076-1078
Number of pages	3
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/b716558g
State	Published - 2008

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title = "Direct evidence for an iron(IV)-oxo porphyrin π-cation radical as an active oxidant in catalytic oxygenation reactions",

abstract = "A high-valent iron(iv)-oxo porphyrin π-cation radical is an active oxidant in the catalytic oxygenation of organic substrates by an iron(iii) porphyrin complex and peracids, whereas an iron(iii)-oxidant porphyrin adduct is a sluggish oxidant in iron porphyrin model reactions.",

author = "Han, {Ah Rim} and {Jin Jeong}, Yu and Yaeun Kang and {Yoon Lee}, Jung and {Sook Seo}, Mi and Wonwoo Nam",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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AU - Han, Ah Rim

AU - Jin Jeong, Yu

AU - Kang, Yaeun

AU - Yoon Lee, Jung

AU - Sook Seo, Mi

AU - Nam, Wonwoo

PY - 2008

Y1 - 2008

N2 - A high-valent iron(iv)-oxo porphyrin π-cation radical is an active oxidant in the catalytic oxygenation of organic substrates by an iron(iii) porphyrin complex and peracids, whereas an iron(iii)-oxidant porphyrin adduct is a sluggish oxidant in iron porphyrin model reactions.

AB - A high-valent iron(iv)-oxo porphyrin π-cation radical is an active oxidant in the catalytic oxygenation of organic substrates by an iron(iii) porphyrin complex and peracids, whereas an iron(iii)-oxidant porphyrin adduct is a sluggish oxidant in iron porphyrin model reactions.

UR - http://www.scopus.com/inward/record.url?scp=39749096483&partnerID=8YFLogxK

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DO - 10.1039/b716558g

M3 - Article

C2 - 18292895

AN - SCOPUS:39749096483

SN - 1359-7345

SP - 1076

EP - 1078

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Direct evidence for an iron(IV)-oxo porphyrin π-cation radical as an active oxidant in catalytic oxygenation reactions

Abstract

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