Direct evidence for an iron(IV)-oxo porphyrin π-cation radical as an active oxidant in catalytic oxygenation reactions

Ah Rim Han, Yu Jin Jeong, Yaeun Kang, Jung Yoon Lee, Mi Sook Seo, Wonwoo Nam

Research output: Contribution to journalArticlepeer-review

45 Scopus citations

Abstract

A high-valent iron(iv)-oxo porphyrin π-cation radical is an active oxidant in the catalytic oxygenation of organic substrates by an iron(iii) porphyrin complex and peracids, whereas an iron(iii)-oxidant porphyrin adduct is a sluggish oxidant in iron porphyrin model reactions.

Original languageEnglish
Pages (from-to)1076-1078
Number of pages3
JournalChemical Communications
Issue number9
DOIs
StatePublished - 2008

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