Dimethanoltetrakis[5,10,15,20-tetrakis-(2,6-dichlorophenyl)porphinato] manganese(III) hexacyanooctaselenidorhenate(III) tridecahydrate

Seon Mi Park; Sehye Kim; Alan J. Lough; Sung Jin Kim; Youngmee Kim

doi:10.1107/S1600536803008547

Dimethanoltetrakis[5,10,15,20-tetrakis-(2,6-dichlorophenyl)porphinato] manganese(III) hexacyanooctaselenidorhenate(III) tridecahydrate

Seon Mi Park, Sehye Kim, Alan J. Lough, Sung Jin Kim, Youngmee Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The crystal structure of the title compound, [Mn(TDC)]₄[Re ₆Se₈(CN)₆]·13H₂O, contains discrete [Re₆Se₈(CN)₆]^4-nd Mn(TDC)⁺ moieties [TDC is the tetrakis(2,6-dichlorophenyl)-porphinate dianion, C₄₄H₂₀Cl₈N₄^2-]. The anion as well as two of the cations lie on crystallographic centers of symmetry. Each Mn(TDC)⁺ cation is octahedral with two axial methanol ligands. The coordinated methanol groups form O-H⋯O hydrogen bonds to solvent water molecules of crystallization in the lattice.

Original language	English
Pages (from-to)	m276-m279
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	5
DOIs	https://doi.org/10.1107/S1600536803008547
State	Published - May 2003

Access to Document

10.1107/S1600536803008547

Cite this

@article{22ffb18f6939424685c34b718ad5a7cc,

title = "Dimethanoltetrakis[5,10,15,20-tetrakis-(2,6-dichlorophenyl)porphinato] manganese(III) hexacyanooctaselenidorhenate(III) tridecahydrate",

abstract = "The crystal structure of the title compound, [Mn(TDC)]4[Re 6Se8(CN)6]·13H2O, contains discrete [Re6Se8(CN)6]4-nd Mn(TDC)+ moieties [TDC is the tetrakis(2,6-dichlorophenyl)-porphinate dianion, C44H20Cl8N42-]. The anion as well as two of the cations lie on crystallographic centers of symmetry. Each Mn(TDC)+ cation is octahedral with two axial methanol ligands. The coordinated methanol groups form O-H⋯O hydrogen bonds to solvent water molecules of crystallization in the lattice.",

author = "Park, {Seon Mi} and Sehye Kim and Lough, {Alan J.} and Kim, {Sung Jin} and Youngmee Kim",

year = "2003",

month = may,

doi = "10.1107/S1600536803008547",

language = "English",

volume = "59",

pages = "m276--m279",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "5",

}

TY - JOUR

T1 - Dimethanoltetrakis[5,10,15,20-tetrakis-(2,6-dichlorophenyl)porphinato] manganese(III) hexacyanooctaselenidorhenate(III) tridecahydrate

AU - Park, Seon Mi

AU - Kim, Sehye

AU - Lough, Alan J.

AU - Kim, Sung Jin

AU - Kim, Youngmee

PY - 2003/5

Y1 - 2003/5

N2 - The crystal structure of the title compound, [Mn(TDC)]4[Re 6Se8(CN)6]·13H2O, contains discrete [Re6Se8(CN)6]4-nd Mn(TDC)+ moieties [TDC is the tetrakis(2,6-dichlorophenyl)-porphinate dianion, C44H20Cl8N42-]. The anion as well as two of the cations lie on crystallographic centers of symmetry. Each Mn(TDC)+ cation is octahedral with two axial methanol ligands. The coordinated methanol groups form O-H⋯O hydrogen bonds to solvent water molecules of crystallization in the lattice.

AB - The crystal structure of the title compound, [Mn(TDC)]4[Re 6Se8(CN)6]·13H2O, contains discrete [Re6Se8(CN)6]4-nd Mn(TDC)+ moieties [TDC is the tetrakis(2,6-dichlorophenyl)-porphinate dianion, C44H20Cl8N42-]. The anion as well as two of the cations lie on crystallographic centers of symmetry. Each Mn(TDC)+ cation is octahedral with two axial methanol ligands. The coordinated methanol groups form O-H⋯O hydrogen bonds to solvent water molecules of crystallization in the lattice.

UR - http://www.scopus.com/inward/record.url?scp=18444378438&partnerID=8YFLogxK

U2 - 10.1107/S1600536803008547

DO - 10.1107/S1600536803008547

M3 - Article

AN - SCOPUS:18444378438

SN - 1600-5368

VL - 59

SP - m276-m279

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 5

ER -

Dimethanoltetrakis[5,10,15,20-tetrakis-(2,6-dichlorophenyl)porphinato] manganese(III) hexacyanooctaselenidorhenate(III) tridecahydrate

Abstract

Access to Document

Fingerprint

Cite this