Dicopper-dioxygen complex supported by asymmetric pentapyridine dinucleating ligand

Yoshimitsu Tachi; Kazuki Aita; Shinichi Teramae; Fumito Tani; Yoshinori Naruta; Shunichi Fukuzumi; Shinobu Itoh

doi:10.1021/ic049524g

Dicopper-dioxygen complex supported by asymmetric pentapyridine dinucleating ligand

Yoshimitsu Tachi, Kazuki Aita, Shinichi Teramae, Fumito Tani, Yoshinori Naruta, Shunichi Fukuzumi, Shinobu Itoh

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

A dicopper(I) complex supported by a novel asymmetric pentapyridine dinucleating ligand, consisting of tetradentate and tridentate metal-binding sites, has been synthesized and characterized. The dicopper(I) complex reacted with molecular oxygen at a low temperature to give an unprecedented μ-peroxo dicopper(II) complex presumably having μ-η¹:η² binding mode, the spectroscopic features and the reactivity of which have been explored in detail.

Original language	English
Pages (from-to)	4558-4560
Number of pages	3
Journal	Inorganic Chemistry
Volume	43
Issue number	15
DOIs	https://doi.org/10.1021/ic049524g
State	Published - 26 Jul 2004

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title = "Dicopper-dioxygen complex supported by asymmetric pentapyridine dinucleating ligand",

abstract = "A dicopper(I) complex supported by a novel asymmetric pentapyridine dinucleating ligand, consisting of tetradentate and tridentate metal-binding sites, has been synthesized and characterized. The dicopper(I) complex reacted with molecular oxygen at a low temperature to give an unprecedented μ-peroxo dicopper(II) complex presumably having μ-η1:η2 binding mode, the spectroscopic features and the reactivity of which have been explored in detail.",

author = "Yoshimitsu Tachi and Kazuki Aita and Shinichi Teramae and Fumito Tani and Yoshinori Naruta and Shunichi Fukuzumi and Shinobu Itoh",

year = "2004",

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T1 - Dicopper-dioxygen complex supported by asymmetric pentapyridine dinucleating ligand

AU - Tachi, Yoshimitsu

AU - Aita, Kazuki

AU - Teramae, Shinichi

AU - Tani, Fumito

AU - Naruta, Yoshinori

AU - Fukuzumi, Shunichi

AU - Itoh, Shinobu

PY - 2004/7/26

Y1 - 2004/7/26

N2 - A dicopper(I) complex supported by a novel asymmetric pentapyridine dinucleating ligand, consisting of tetradentate and tridentate metal-binding sites, has been synthesized and characterized. The dicopper(I) complex reacted with molecular oxygen at a low temperature to give an unprecedented μ-peroxo dicopper(II) complex presumably having μ-η1:η2 binding mode, the spectroscopic features and the reactivity of which have been explored in detail.

AB - A dicopper(I) complex supported by a novel asymmetric pentapyridine dinucleating ligand, consisting of tetradentate and tridentate metal-binding sites, has been synthesized and characterized. The dicopper(I) complex reacted with molecular oxygen at a low temperature to give an unprecedented μ-peroxo dicopper(II) complex presumably having μ-η1:η2 binding mode, the spectroscopic features and the reactivity of which have been explored in detail.

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U2 - 10.1021/ic049524g

DO - 10.1021/ic049524g

M3 - Article

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VL - 43

SP - 4558

EP - 4560

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 15

ER -

Dicopper-dioxygen complex supported by asymmetric pentapyridine dinucleating ligand

Abstract

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