Design of tailored multi-charged phosphorus surface-block dendrimers

Valérie Maraval, Alexandrine Maraval, Grégory Spataro, Anne Marie Caminade, Jean Pierre Majoral, Dong Ha Kim, Wolfgang Knoll

Research output: Contribution to journalArticlepeer-review

27 Scopus citations

Abstract

Polycationic or neutral dendrons of generation 1 to 3 bearing protonated (or not) amino end groups and a vinyl group at the focal point as well as polyanionic or neutral dendrons of generation 1 to 3 decorated with carboxylate or carboxylic groups on their surface and exhibiting a vinyl group at the core were prepared. Addition of ethylenediamine to the vinyl core of dendrons having amino end groups allowed the synthesis of uniquely tailored water-soluble phosphorus bis-dendrons via core to core assembling of dendrons having a vinyl core. In preliminary experiments layer-by-layer deposition of bis-dendrons on silica surface was demonstrated.

Original languageEnglish
Pages (from-to)1731-1736
Number of pages6
JournalNew Journal of Chemistry
Volume30
Issue number12
DOIs
StatePublished - 2006

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