Design and properties of mixed-metal multinuclear molecules. Part II. Novel heterotrinuclear complexes of [AG(PPh3)2]2[CU(mtm)2] and [AG2(dppm)2][CU(mtm)2] (mtm = [bis(methylthio)methylene]malonate and dppm = bis(diphenylphosphino)methane)

Young Jun Park; Youngkyu Do; Kwan Mook Kim; Moon Gun Choi; Moo Jin Jun; Cheal Kim

doi:10.1016/S0277-5387(01)00951-2

Design and properties of mixed-metal multinuclear molecules. Part II. Novel heterotrinuclear complexes of [AG(PPh₃)₂]₂[CU(mtm)₂] and [AG₂(dppm)₂][CU(mtm)₂] (mtm = [bis(methylthio)methylene]malonate and dppm = bis(diphenylphosphino)methane)

Young Jun Park, Youngkyu Do, Kwan Mook Kim, Moon Gun Choi, Moo Jin Jun, Cheal Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Novel trinuclear disilver(I)-copper(II) complexes, [Ag(PPh₃)₂]₂[Cu(mtm)₂] (1) and [Ag₂(dppm)₂][Cu(mtm)₂] (2) (mtm = [bis(-methylthio)methylene]malonate, dppm = bis(diphenylphosphino)methane) have been prepared and characterized by a single-crystal X-ray structure analysis. In the complex 1, a silver atom is coordinated to each of the two carboxylate oxygens with different bond distances of 2.325(5) Å (Ag-O(1)) and 2.653(6) Å (Ag-O(2)). In the case of the complex 2, two silver atoms are bridged by two dppm ligands separated by 3.0130(9) Å and Ag(1) has bonded to O(5) (2.442(5) Å). Interestingly, Ag(2) has bonded to O(4) (2.325(5) Å) which is not a coordinated carboxylate oxygen bonded to copper(II) atom. Interaction between silver(I)-thioether group was not observed in 1 and 2.

Original language	English
Pages (from-to)	33-37
Number of pages	5
Journal	Polyhedron
Volume	21
Issue number	1
DOIs	https://doi.org/10.1016/S0277-5387(01)00951-2
State	Published - 15 Jan 2002

Bibliographical note

Funding Information:
The authors wish to acknowledge the financial support of the Korea Research Foundation made in the program year of 1997 (Grant No. 1997-011-D00018).

Keywords

Carboxylate
Copper(II)
Silver(I)
Single crystal structures
Thioether
Trinuclear complexes

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Park, Y. J., Do, Y., Kim, K. M., Choi, M. G., Jun, M. J., & Kim, C. (2002). Design and properties of mixed-metal multinuclear molecules. Part II. Novel heterotrinuclear complexes of [AG(PPh₃)₂]₂[CU(mtm)₂] and [AG₂(dppm)₂][CU(mtm)₂] (mtm = [bis(methylthio)methylene]malonate and dppm = bis(diphenylphosphino)methane). Polyhedron, 21(1), 33-37. https://doi.org/10.1016/S0277-5387(01)00951-2

@article{25e7731a518341869a77e13d24548361,

title = "Design and properties of mixed-metal multinuclear molecules. Part II. Novel heterotrinuclear complexes of [AG(PPh3)2]2[CU(mtm)2] and [AG2(dppm)2][CU(mtm)2] (mtm = [bis(methylthio)methylene]malonate and dppm = bis(diphenylphosphino)methane)",

abstract = "Novel trinuclear disilver(I)-copper(II) complexes, [Ag(PPh3)2]2[Cu(mtm)2] (1) and [Ag2(dppm)2][Cu(mtm)2] (2) (mtm = [bis(-methylthio)methylene]malonate, dppm = bis(diphenylphosphino)methane) have been prepared and characterized by a single-crystal X-ray structure analysis. In the complex 1, a silver atom is coordinated to each of the two carboxylate oxygens with different bond distances of 2.325(5) {\AA} (Ag-O(1)) and 2.653(6) {\AA} (Ag-O(2)). In the case of the complex 2, two silver atoms are bridged by two dppm ligands separated by 3.0130(9) {\AA} and Ag(1) has bonded to O(5) (2.442(5) {\AA}). Interestingly, Ag(2) has bonded to O(4) (2.325(5) {\AA}) which is not a coordinated carboxylate oxygen bonded to copper(II) atom. Interaction between silver(I)-thioether group was not observed in 1 and 2.",

keywords = "Carboxylate, Copper(II), Silver(I), Single crystal structures, Thioether, Trinuclear complexes",

author = "Park, {Young Jun} and Youngkyu Do and Kim, {Kwan Mook} and Choi, {Moon Gun} and Jun, {Moo Jin} and Cheal Kim",

note = "Funding Information: The authors wish to acknowledge the financial support of the Korea Research Foundation made in the program year of 1997 (Grant No. 1997-011-D00018). ",

year = "2002",

month = jan,

day = "15",

doi = "10.1016/S0277-5387(01)00951-2",

language = "English",

volume = "21",

pages = "33--37",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "1",

}

Park, YJ, Do, Y, Kim, KM, Choi, MG, Jun, MJ & Kim, C 2002, 'Design and properties of mixed-metal multinuclear molecules. Part II. Novel heterotrinuclear complexes of [AG(PPh₃)₂]₂[CU(mtm)₂] and [AG₂(dppm)₂][CU(mtm)₂] (mtm = [bis(methylthio)methylene]malonate and dppm = bis(diphenylphosphino)methane)', Polyhedron, vol. 21, no. 1, pp. 33-37. https://doi.org/10.1016/S0277-5387(01)00951-2

Design and properties of mixed-metal multinuclear molecules. Part II. Novel heterotrinuclear complexes of [AG(PPh₃)₂]₂[CU(mtm)₂] and [AG₂(dppm)₂][CU(mtm)₂] (mtm = [bis(methylthio)methylene]malonate and dppm = bis(diphenylphosphino)methane). / Park, Young Jun; Do, Youngkyu; Kim, Kwan Mook et al.
In: Polyhedron, Vol. 21, No. 1, 15.01.2002, p. 33-37.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Design and properties of mixed-metal multinuclear molecules. Part II. Novel heterotrinuclear complexes of [AG(PPh3)2]2[CU(mtm)2] and [AG2(dppm)2][CU(mtm)2] (mtm = [bis(methylthio)methylene]malonate and dppm = bis(diphenylphosphino)methane)

AU - Park, Young Jun

AU - Do, Youngkyu

AU - Kim, Kwan Mook

AU - Choi, Moon Gun

AU - Jun, Moo Jin

AU - Kim, Cheal

N1 - Funding Information: The authors wish to acknowledge the financial support of the Korea Research Foundation made in the program year of 1997 (Grant No. 1997-011-D00018).

PY - 2002/1/15

Y1 - 2002/1/15

N2 - Novel trinuclear disilver(I)-copper(II) complexes, [Ag(PPh3)2]2[Cu(mtm)2] (1) and [Ag2(dppm)2][Cu(mtm)2] (2) (mtm = [bis(-methylthio)methylene]malonate, dppm = bis(diphenylphosphino)methane) have been prepared and characterized by a single-crystal X-ray structure analysis. In the complex 1, a silver atom is coordinated to each of the two carboxylate oxygens with different bond distances of 2.325(5) Å (Ag-O(1)) and 2.653(6) Å (Ag-O(2)). In the case of the complex 2, two silver atoms are bridged by two dppm ligands separated by 3.0130(9) Å and Ag(1) has bonded to O(5) (2.442(5) Å). Interestingly, Ag(2) has bonded to O(4) (2.325(5) Å) which is not a coordinated carboxylate oxygen bonded to copper(II) atom. Interaction between silver(I)-thioether group was not observed in 1 and 2.

AB - Novel trinuclear disilver(I)-copper(II) complexes, [Ag(PPh3)2]2[Cu(mtm)2] (1) and [Ag2(dppm)2][Cu(mtm)2] (2) (mtm = [bis(-methylthio)methylene]malonate, dppm = bis(diphenylphosphino)methane) have been prepared and characterized by a single-crystal X-ray structure analysis. In the complex 1, a silver atom is coordinated to each of the two carboxylate oxygens with different bond distances of 2.325(5) Å (Ag-O(1)) and 2.653(6) Å (Ag-O(2)). In the case of the complex 2, two silver atoms are bridged by two dppm ligands separated by 3.0130(9) Å and Ag(1) has bonded to O(5) (2.442(5) Å). Interestingly, Ag(2) has bonded to O(4) (2.325(5) Å) which is not a coordinated carboxylate oxygen bonded to copper(II) atom. Interaction between silver(I)-thioether group was not observed in 1 and 2.

KW - Carboxylate

KW - Copper(II)

KW - Silver(I)

KW - Single crystal structures

KW - Thioether

KW - Trinuclear complexes

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U2 - 10.1016/S0277-5387(01)00951-2

DO - 10.1016/S0277-5387(01)00951-2

M3 - Article

AN - SCOPUS:0037080472

SN - 0277-5387

VL - 21

SP - 33

EP - 37

JO - Polyhedron

JF - Polyhedron

IS - 1

ER -