Crystalline 1H-l,2,3-Triazol-5-ylidenes: New stable mesoionic carbenes (MICs)

Gregorio Guisado-Barrios, Jean Bouffard, Bruno Donnadieu, Guy Bertrand

Research output: Contribution to journalArticlepeer-review

326 Scopus citations

Abstract

Figure Persentation Click makes MICs: A short modular synthesis allows the preparation of novel stable heterocycles that feature a lone pair of electrons on a carbon center. The donor properties of these mesoionic com-pounds are greater than those of classical N-heterocyclic carbenes; they are accessible by deprotonation of the corresponding conjugate acids using comparatively mild bases.

Original languageEnglish
Pages (from-to)4759-4762
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number28
DOIs
StatePublished - 28 Jun 2010

Keywords

  • Carbene ligands
  • Carbenes
  • Click chemistry
  • Mesoionic compounds
  • Triazoles

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