Crystal structure of the bioctahedral cluster complex K 6[Re 12CS 17(CN) 6]•2CH 3OH• 10H 2O

Yu V. Mironov; S. J. Kim; V. E. Fedorov

doi:10.1007/s10947-009-0052-9

Crystal structure of the bioctahedral cluster complex K ₆[Re ₁₂CS ₁₇(CN) ₆]•2CH ₃OH• 10H ₂O

Yu V. Mironov, S. J. Kim, V. E. Fedorov

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

Abstract

The cluster complex of K ₆[Re ₁₂CS ₁₇(CN) ₆]•2CH ₃OH•10H ₂O composition is separated by recrystallization of the K ₆[Re ₁₂CS ₁₇(CN) ₆]•20H ₂O compound from methanol. The compound crystallizes in hexagonal space group P-6m2 with unit cell parameters: a = 10.9932(14) Å, c = 14.631(4) Å, V = 1531.3(5) Å ³, Z = 1, and d _calc = 3.720 g/cm ³.

Original language	English
Pages (from-to)	365-367
Number of pages	3
Journal	Journal of Structural Chemistry
Volume	50
Issue number	2
DOIs	https://doi.org/10.1007/s10947-009-0052-9
State	Published - Apr 2009

Bibliographical note

Funding Information:
The work was supported by RFBR (grant 07-03-00912) and Korean Scientific Foundation Seoul Research and Business Development Program(10816).

Keywords

Bioctahedral thiocyanate cluster
Crystal structure
Rhenium
Synthesis

Access to Document

10.1007/s10947-009-0052-9

Cite this

@article{761fb28509494c8e838c9208bf349755,

title = "Crystal structure of the bioctahedral cluster complex K 6[Re 12CS 17(CN) 6]•2CH 3OH• 10H 2O",

abstract = "The cluster complex of K 6[Re 12CS 17(CN) 6]•2CH 3OH•10H 2O composition is separated by recrystallization of the K 6[Re 12CS 17(CN) 6]•20H 2O compound from methanol. The compound crystallizes in hexagonal space group P-6m2 with unit cell parameters: a = 10.9932(14) {\AA}, c = 14.631(4) {\AA}, V = 1531.3(5) {\AA} 3, Z = 1, and d calc = 3.720 g/cm 3.",

keywords = "Bioctahedral thiocyanate cluster, Crystal structure, Rhenium, Synthesis",

author = "Mironov, {Yu V.} and Kim, {S. J.} and Fedorov, {V. E.}",

note = "Funding Information: The work was supported by RFBR (grant 07-03-00912) and Korean Scientific Foundation Seoul Research and Business Development Program(10816).",

year = "2009",

month = apr,

doi = "10.1007/s10947-009-0052-9",

language = "English",

volume = "50",

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journal = "Journal of Structural Chemistry",

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T1 - Crystal structure of the bioctahedral cluster complex K 6[Re 12CS 17(CN) 6]•2CH 3OH• 10H 2O

AU - Mironov, Yu V.

AU - Kim, S. J.

AU - Fedorov, V. E.

N1 - Funding Information: The work was supported by RFBR (grant 07-03-00912) and Korean Scientific Foundation Seoul Research and Business Development Program(10816).

PY - 2009/4

Y1 - 2009/4

N2 - The cluster complex of K 6[Re 12CS 17(CN) 6]•2CH 3OH•10H 2O composition is separated by recrystallization of the K 6[Re 12CS 17(CN) 6]•20H 2O compound from methanol. The compound crystallizes in hexagonal space group P-6m2 with unit cell parameters: a = 10.9932(14) Å, c = 14.631(4) Å, V = 1531.3(5) Å 3, Z = 1, and d calc = 3.720 g/cm 3.

AB - The cluster complex of K 6[Re 12CS 17(CN) 6]•2CH 3OH•10H 2O composition is separated by recrystallization of the K 6[Re 12CS 17(CN) 6]•20H 2O compound from methanol. The compound crystallizes in hexagonal space group P-6m2 with unit cell parameters: a = 10.9932(14) Å, c = 14.631(4) Å, V = 1531.3(5) Å 3, Z = 1, and d calc = 3.720 g/cm 3.

KW - Bioctahedral thiocyanate cluster

KW - Crystal structure

KW - Rhenium

KW - Synthesis

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