Crystal structure of Cs[Gd(H2O)4Re6Te 8(CN)6]•4H2O

M. S. Tarasenko; N. G. Naumov; A. V. Virovets; S. J. Kim; V. E. Fedorov

doi:10.1007/s10947-008-0191-4

Crystal structure of Cs[Gd(H₂O)₄Re₆Te ₈(CN)₆]•4H₂O

M. S. Tarasenko, N. G. Naumov, A. V. Virovets, S. J. Kim, V. E. Fedorov

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The structure of the salt Cs[Gd(H₂O)₄Re ₆Te₈(CN)₆]•4H₂O (space group P-1, a = 9.436(5) Å, b = 12.365(7) Å, c = 15.187(8)Å, α = 89.104(10)°, β = 86.996(10)°, γ = 82.304(9)°) has been established by single crystal XRD. The structure of the compound features layers involving Gd³⁺ cations bound to cluster anions [Re ₆Te₈(CN)₆]^4- through cyanide groups. The interlayer space contains cesium cations and crystallization water molecules.

Original language	English
Pages (from-to)	1128-1131
Number of pages	4
Journal	Journal of Structural Chemistry
Volume	49
Issue number	6
DOIs	https://doi.org/10.1007/s10947-008-0191-4
State	Published - Nov 2008

Bibliographical note

Funding Information:
This work was supported by Korea Science and Engineering Foundation (grant ABRLR14-2003-014-01001-0), Taiwan NSC and RFBR (grants 06-03-89503-NNS and 95WFD0300050 (Contract No. RP06N02-2)).

Keywords

Crystal structure
Cyanide complex
Gadolinium
Octahedral cluster
Rhenium

Access to Document

10.1007/s10947-008-0191-4

Cite this

@article{ec7c99466f264335bb58491d0f00ea0f,

title = "Crystal structure of Cs[Gd(H2O)4Re6Te 8(CN)6]•4H2O",

abstract = "The structure of the salt Cs[Gd(H2O)4Re 6Te8(CN)6]•4H2O (space group P-1, a = 9.436(5) {\AA}, b = 12.365(7) {\AA}, c = 15.187(8){\AA}, α = 89.104(10)°, β = 86.996(10)°, γ = 82.304(9)°) has been established by single crystal XRD. The structure of the compound features layers involving Gd3+ cations bound to cluster anions [Re 6Te8(CN)6]4- through cyanide groups. The interlayer space contains cesium cations and crystallization water molecules.",

keywords = "Crystal structure, Cyanide complex, Gadolinium, Octahedral cluster, Rhenium",

author = "Tarasenko, {M. S.} and Naumov, {N. G.} and Virovets, {A. V.} and Kim, {S. J.} and Fedorov, {V. E.}",

note = "Funding Information: This work was supported by Korea Science and Engineering Foundation (grant ABRLR14-2003-014-01001-0), Taiwan NSC and RFBR (grants 06-03-89503-NNS and 95WFD0300050 (Contract No. RP06N02-2)).",

year = "2008",

month = nov,

doi = "10.1007/s10947-008-0191-4",

language = "English",

volume = "49",

pages = "1128--1131",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Pleiades Publishing",

number = "6",

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TY - JOUR

T1 - Crystal structure of Cs[Gd(H2O)4Re6Te 8(CN)6]•4H2O

AU - Tarasenko, M. S.

AU - Naumov, N. G.

AU - Virovets, A. V.

AU - Kim, S. J.

AU - Fedorov, V. E.

N1 - Funding Information: This work was supported by Korea Science and Engineering Foundation (grant ABRLR14-2003-014-01001-0), Taiwan NSC and RFBR (grants 06-03-89503-NNS and 95WFD0300050 (Contract No. RP06N02-2)).

PY - 2008/11

Y1 - 2008/11

N2 - The structure of the salt Cs[Gd(H2O)4Re 6Te8(CN)6]•4H2O (space group P-1, a = 9.436(5) Å, b = 12.365(7) Å, c = 15.187(8)Å, α = 89.104(10)°, β = 86.996(10)°, γ = 82.304(9)°) has been established by single crystal XRD. The structure of the compound features layers involving Gd3+ cations bound to cluster anions [Re 6Te8(CN)6]4- through cyanide groups. The interlayer space contains cesium cations and crystallization water molecules.

AB - The structure of the salt Cs[Gd(H2O)4Re 6Te8(CN)6]•4H2O (space group P-1, a = 9.436(5) Å, b = 12.365(7) Å, c = 15.187(8)Å, α = 89.104(10)°, β = 86.996(10)°, γ = 82.304(9)°) has been established by single crystal XRD. The structure of the compound features layers involving Gd3+ cations bound to cluster anions [Re 6Te8(CN)6]4- through cyanide groups. The interlayer space contains cesium cations and crystallization water molecules.

KW - Crystal structure

KW - Cyanide complex

KW - Gadolinium

KW - Octahedral cluster

KW - Rhenium

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U2 - 10.1007/s10947-008-0191-4

DO - 10.1007/s10947-008-0191-4

M3 - Article

AN - SCOPUS:59549095197

SN - 0022-4766

VL - 49

SP - 1128

EP - 1131

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

IS - 6

ER -