Crystal structure of Cs[Gd(H2O)4Re6Te 8(CN)6]•4H2O

M. S. Tarasenko, N. G. Naumov, A. V. Virovets, S. J. Kim, V. E. Fedorov

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

The structure of the salt Cs[Gd(H2O)4Re 6Te8(CN)6]•4H2O (space group P-1, a = 9.436(5) Å, b = 12.365(7) Å, c = 15.187(8)Å, α = 89.104(10)°, β = 86.996(10)°, γ = 82.304(9)°) has been established by single crystal XRD. The structure of the compound features layers involving Gd3+ cations bound to cluster anions [Re 6Te8(CN)6]4- through cyanide groups. The interlayer space contains cesium cations and crystallization water molecules.

Original languageEnglish
Pages (from-to)1128-1131
Number of pages4
JournalJournal of Structural Chemistry
Volume49
Issue number6
DOIs
StatePublished - Nov 2008

Keywords

  • Crystal structure
  • Cyanide complex
  • Gadolinium
  • Octahedral cluster
  • Rhenium

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