TY - JOUR
T1 - Correcting the classical dipolar demagnetizing field in solution NMR
AU - Warren, W. S.
AU - Lee, S.
AU - Richter, W.
AU - Vathyam, S.
N1 - Funding Information:
This work was supported by the NIH under grant GM35253.
PY - 1995/12/22
Y1 - 1995/12/22
N2 - Numerous observations of anomalous intermolecular multiple-quantum and cross correlation peaks in solution NMR have led to a variety of theoretical treatments, some involving radiation damping or modified classical Bloch equations, others involving full quantum mechanical derivations. We explore the theoretical underpinnings of the classical model, which invokes the dipolar demagnetizing field, and correct a significant omission in the original formulation which has been propagated in later papers. This correction gives good agreement between theory and experiment.
AB - Numerous observations of anomalous intermolecular multiple-quantum and cross correlation peaks in solution NMR have led to a variety of theoretical treatments, some involving radiation damping or modified classical Bloch equations, others involving full quantum mechanical derivations. We explore the theoretical underpinnings of the classical model, which invokes the dipolar demagnetizing field, and correct a significant omission in the original formulation which has been propagated in later papers. This correction gives good agreement between theory and experiment.
UR - http://www.scopus.com/inward/record.url?scp=0000987990&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(95)01184-5
DO - 10.1016/0009-2614(95)01184-5
M3 - Article
AN - SCOPUS:0000987990
SN - 0009-2614
VL - 247
SP - 207
EP - 214
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 3
ER -