Contrasting effects of axial ligands on electron-transfer versus proton-coupled electron-transfer reactions of nonheme oxoiron(IV) complexes

Engineering & Materials Science

• Proton transfer 100%
• Ligands 72%
• Electrons 55%
• Protons 15%
• Derivatives 6%
• Rate constants 5%
• Deceleration 4%
• Atoms 4%
• Acids 3%
• Hydrogen 3%
• Electrodes 3%

Chemical Compounds

• Electron Transfer 38%
• Ligand 24%
• Ferrocene 11%
• Reorganization Energy 7%
• Reduction Potential 6%
• Electron Donor 5%
• Hydrogen Atom 5%
• Donor 4%
• Rate Constant 3%
• Strength 3%
• Behavior as Electrode 3%
• Reduction 2%
• Acid 2%