Construction, photoluminescence, and catalytic reactivity study of Cd(II) complexes containing amide ligand with hydrogen-bond capable backbone: 1-Dimensional looped chain

Tae Geum Lee; Ju Hoon Lee; Min Young Hyun; Seung Pyo Jang; Hong Gyu Lee; Cheal Kim; Sung Jin Kim; Youngmee Kim

doi:10.1016/j.inoche.2010.08.025

Construction, photoluminescence, and catalytic reactivity study of Cd(II) complexes containing amide ligand with hydrogen-bond capable backbone: 1-Dimensional looped chain

Tae Geum Lee, Ju Hoon Lee, Min Young Hyun, Seung Pyo Jang, Hong Gyu Lee, Cheal Kim, Sung Jin Kim, Youngmee Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Three new Cd(II) complexes containing 3-bpdb ligands with amide moiety as hydrogen-bond capable backbone, formulated as [Cd(3-bpdb)X₂] _n (3-bpdb = N,N′-dipyridin-3-ylpyridine-2,6-dicarboxamide, X = Cl (1), Br (2), and I (3)), have been synthesized. All three compounds show 1-dimensional looped chain structures, and intra- and inter-molecular hydrogen bonding interactions provide 2-dimensional sheets. Among three pausible conformers of ligand 3-bpdb, all three halide compounds show only anti-anti conformation to provide 1-dimensional looped chains. In addition, emissions of compounds 1 and 2 were observed at 424 nm and 431 nm, respectively, suggesting that they might be a good candidate for a potential hybrid inorganic-organic photoactive material. Moreover, compounds 1-3 carried out an efficient transesterification of vinyl acetate.

Original language	English
Pages (from-to)	1493-1496
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	13
Issue number	12
DOIs	https://doi.org/10.1016/j.inoche.2010.08.025
State	Published - Dec 2010

Bibliographical note

Funding Information:
Financial support from Korea Ministry Environment “ET-Human resource development Project”, Korean Science & Engineering Foundation (R01-2008-000-20704-0 and 2009-0074066), Converging Research Center Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2009-0082832), and the SRC program of MOST/KOSEF through the Center for Intelligent Nano-Bio Materials at Ewha Womans University (R11-2005-008-00000-0) is gratefully acknowledged.

Keywords

1-Dimensional looped chain
Catalytic reactivity
Cd(II) complexes
N,N′-dipyridin-3-ylpyridine-2,6-dicarboxamide
Photoluminescence

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10.1016/j.inoche.2010.08.025

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Lee, T. G., Lee, J. H., Hyun, M. Y., Jang, S. P., Lee, H. G., Kim, C., Kim, S. J., & Kim, Y. (2010). Construction, photoluminescence, and catalytic reactivity study of Cd(II) complexes containing amide ligand with hydrogen-bond capable backbone: 1-Dimensional looped chain. Inorganic Chemistry Communications, 13(12), 1493-1496. https://doi.org/10.1016/j.inoche.2010.08.025

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title = "Construction, photoluminescence, and catalytic reactivity study of Cd(II) complexes containing amide ligand with hydrogen-bond capable backbone: 1-Dimensional looped chain",

abstract = "Three new Cd(II) complexes containing 3-bpdb ligands with amide moiety as hydrogen-bond capable backbone, formulated as [Cd(3-bpdb)X2] n (3-bpdb = N,N′-dipyridin-3-ylpyridine-2,6-dicarboxamide, X = Cl (1), Br (2), and I (3)), have been synthesized. All three compounds show 1-dimensional looped chain structures, and intra- and inter-molecular hydrogen bonding interactions provide 2-dimensional sheets. Among three pausible conformers of ligand 3-bpdb, all three halide compounds show only anti-anti conformation to provide 1-dimensional looped chains. In addition, emissions of compounds 1 and 2 were observed at 424 nm and 431 nm, respectively, suggesting that they might be a good candidate for a potential hybrid inorganic-organic photoactive material. Moreover, compounds 1-3 carried out an efficient transesterification of vinyl acetate.",

keywords = "1-Dimensional looped chain, Catalytic reactivity, Cd(II) complexes, N,N′-dipyridin-3-ylpyridine-2,6-dicarboxamide, Photoluminescence",

author = "Lee, {Tae Geum} and Lee, {Ju Hoon} and Hyun, {Min Young} and Jang, {Seung Pyo} and Lee, {Hong Gyu} and Cheal Kim and Kim, {Sung Jin} and Youngmee Kim",

note = "Funding Information: Financial support from Korea Ministry Environment “ET-Human resource development Project”, Korean Science & Engineering Foundation (R01-2008-000-20704-0 and 2009-0074066), Converging Research Center Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2009-0082832), and the SRC program of MOST/KOSEF through the Center for Intelligent Nano-Bio Materials at Ewha Womans University (R11-2005-008-00000-0) is gratefully acknowledged. ",

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doi = "10.1016/j.inoche.2010.08.025",

language = "English",

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Construction, photoluminescence, and catalytic reactivity study of Cd(II) complexes containing amide ligand with hydrogen-bond capable backbone: 1-Dimensional looped chain. / Lee, Tae Geum; Lee, Ju Hoon; Hyun, Min Young et al.
In: Inorganic Chemistry Communications, Vol. 13, No. 12, 12.2010, p. 1493-1496.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Construction, photoluminescence, and catalytic reactivity study of Cd(II) complexes containing amide ligand with hydrogen-bond capable backbone

T2 - 1-Dimensional looped chain

AU - Lee, Tae Geum

AU - Lee, Ju Hoon

AU - Hyun, Min Young

AU - Jang, Seung Pyo

AU - Lee, Hong Gyu

AU - Kim, Cheal

AU - Kim, Sung Jin

AU - Kim, Youngmee

N1 - Funding Information: Financial support from Korea Ministry Environment “ET-Human resource development Project”, Korean Science & Engineering Foundation (R01-2008-000-20704-0 and 2009-0074066), Converging Research Center Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2009-0082832), and the SRC program of MOST/KOSEF through the Center for Intelligent Nano-Bio Materials at Ewha Womans University (R11-2005-008-00000-0) is gratefully acknowledged.

PY - 2010/12

Y1 - 2010/12

N2 - Three new Cd(II) complexes containing 3-bpdb ligands with amide moiety as hydrogen-bond capable backbone, formulated as [Cd(3-bpdb)X2] n (3-bpdb = N,N′-dipyridin-3-ylpyridine-2,6-dicarboxamide, X = Cl (1), Br (2), and I (3)), have been synthesized. All three compounds show 1-dimensional looped chain structures, and intra- and inter-molecular hydrogen bonding interactions provide 2-dimensional sheets. Among three pausible conformers of ligand 3-bpdb, all three halide compounds show only anti-anti conformation to provide 1-dimensional looped chains. In addition, emissions of compounds 1 and 2 were observed at 424 nm and 431 nm, respectively, suggesting that they might be a good candidate for a potential hybrid inorganic-organic photoactive material. Moreover, compounds 1-3 carried out an efficient transesterification of vinyl acetate.

AB - Three new Cd(II) complexes containing 3-bpdb ligands with amide moiety as hydrogen-bond capable backbone, formulated as [Cd(3-bpdb)X2] n (3-bpdb = N,N′-dipyridin-3-ylpyridine-2,6-dicarboxamide, X = Cl (1), Br (2), and I (3)), have been synthesized. All three compounds show 1-dimensional looped chain structures, and intra- and inter-molecular hydrogen bonding interactions provide 2-dimensional sheets. Among three pausible conformers of ligand 3-bpdb, all three halide compounds show only anti-anti conformation to provide 1-dimensional looped chains. In addition, emissions of compounds 1 and 2 were observed at 424 nm and 431 nm, respectively, suggesting that they might be a good candidate for a potential hybrid inorganic-organic photoactive material. Moreover, compounds 1-3 carried out an efficient transesterification of vinyl acetate.

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KW - N,N′-dipyridin-3-ylpyridine-2,6-dicarboxamide

KW - Photoluminescence

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DO - 10.1016/j.inoche.2010.08.025

M3 - Article

AN - SCOPUS:78649334134

SN - 1387-7003

VL - 13

SP - 1493

EP - 1496

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 12

ER -

Construction, photoluminescence, and catalytic reactivity study of Cd(II) complexes containing amide ligand with hydrogen-bond capable backbone: 1-Dimensional looped chain

Abstract

Bibliographical note

Keywords

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