Construction of crystal structures of metal(II)-benzoates (M = Mn, Ni, Co, Cu, Zn, and Cd) and 1,2-bis(4-pyridyl)ethane: Effects of metal coordination modes and their catalytic activities

Soo Hyun Kim; Byeong Kwon Park; Young Joo Song; Seung Man Yu; Hyo Geun Koo; Eun Young Kim; Jung In Poong; Ju Hoon Lee; Cheal Kim; Sung Jin Kim; Youngmee Kim

doi:10.1016/j.ica.2009.06.008

Construction of crystal structures of metal(II)-benzoates (M = Mn, Ni, Co, Cu, Zn, and Cd) and 1,2-bis(4-pyridyl)ethane: Effects of metal coordination modes and their catalytic activities

Soo Hyun Kim, Byeong Kwon Park, Young Joo Song, Seung Man Yu, Hyo Geun Koo, Eun Young Kim, Jung In Poong, Ju Hoon Lee, Cheal Kim, Sung Jin Kim, Youngmee Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Five polymeric metal(II)-benzoate complexes of formula [Mn(O₂CPh)₂(CH₃OH)₂(bpa)]_n (1-Mn), [Co(O₂CPh)₂(H₂O)(bpa)_1.5]_n (2-Co), [Ni(O₂CPh)₂(H₂O)(bpa)_1.5]_n (3-Ni), [Cu(O₂CPh)₂(CH₃OH)₂(bpa)]_n (4-Cu), and [Cd(O₂CPh)₂(bpa)_1.5]_n (6-Cd) have been synthesized and characterized (bpa = 1,2-bis(4-pyridyl)ethane). They showed two kinds of structures: parallelogram-like two-dimensional sheets for Co, Ni, and Cd, and one-dimensional chains for Mn, Cu, and Zn. Since similar structures provide similar coordination geometries, the structures depend on the coordination geometries of metal ions. The compounds 1-Mn, 2-Co, 4-Cu, 5-Zn, and 6-Cd have catalyzed efficiently the transesterification of a variety of esters, while 3-Ni has displayed a very slow conversion. The reactivity of catalyst 6-Cd containing Cd ion, well known as an inert metal ion for the ligand substitution, was found to be comparable to that of 5-Zn. The reactivities of the compounds used in this study are in the order of 5-Zn > 6-Cd > 1-Mn > 4-Cu > 2-Co ≫ 3-Ni, indicating that the non-redox metal-containing compounds (5-Zn and 6-Cd) show better activity than the redox-active metal-containing compounds (1-Mn, 4-Cu, 2-Co, and 3-Ni).

Original language	English
Pages (from-to)	4119-4126
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	362
Issue number	11
DOIs	https://doi.org/10.1016/j.ica.2009.06.008
State	Published - 15 Aug 2009

Bibliographical note

Funding Information:
Financial support from Korea Ministry Environment “ET-Human resource development Project”, the Korea Research Foundation (2007-314-C00159), the Korean Science & Engineering Foundation (R01-2008-000-20704-0), The SEOUL R&BD Program, and the SRC program of the Korea Science and Engineering Foundation (KOSEF) through the Center for Intelligent Nano-Bio Materials at Ewha Womans University (Grant R11-2005-008-00000-0) is gratefully acknowledged.

Keywords

Catalytic activities
Coordination polymers
Metal coordination modes
Metal-benzoates
Transesterification

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10.1016/j.ica.2009.06.008

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Kim, S. H., Park, B. K., Song, Y. J., Yu, S. M., Koo, H. G., Kim, E. Y., Poong, J. I., Lee, J. H., Kim, C., Kim, S. J., & Kim, Y. (2009). Construction of crystal structures of metal(II)-benzoates (M = Mn, Ni, Co, Cu, Zn, and Cd) and 1,2-bis(4-pyridyl)ethane: Effects of metal coordination modes and their catalytic activities. Inorganica Chimica Acta, 362(11), 4119-4126. https://doi.org/10.1016/j.ica.2009.06.008

@article{219b0d6274c94fbc957a0b38d1c7f131,

title = "Construction of crystal structures of metal(II)-benzoates (M = Mn, Ni, Co, Cu, Zn, and Cd) and 1,2-bis(4-pyridyl)ethane: Effects of metal coordination modes and their catalytic activities",

abstract = "Five polymeric metal(II)-benzoate complexes of formula [Mn(O2CPh)2(CH3OH)2(bpa)]n (1-Mn), [Co(O2CPh)2(H2O)(bpa)1.5]n (2-Co), [Ni(O2CPh)2(H2O)(bpa)1.5]n (3-Ni), [Cu(O2CPh)2(CH3OH)2(bpa)]n (4-Cu), and [Cd(O2CPh)2(bpa)1.5]n (6-Cd) have been synthesized and characterized (bpa = 1,2-bis(4-pyridyl)ethane). They showed two kinds of structures: parallelogram-like two-dimensional sheets for Co, Ni, and Cd, and one-dimensional chains for Mn, Cu, and Zn. Since similar structures provide similar coordination geometries, the structures depend on the coordination geometries of metal ions. The compounds 1-Mn, 2-Co, 4-Cu, 5-Zn, and 6-Cd have catalyzed efficiently the transesterification of a variety of esters, while 3-Ni has displayed a very slow conversion. The reactivity of catalyst 6-Cd containing Cd ion, well known as an inert metal ion for the ligand substitution, was found to be comparable to that of 5-Zn. The reactivities of the compounds used in this study are in the order of 5-Zn > 6-Cd > 1-Mn > 4-Cu > 2-Co ≫ 3-Ni, indicating that the non-redox metal-containing compounds (5-Zn and 6-Cd) show better activity than the redox-active metal-containing compounds (1-Mn, 4-Cu, 2-Co, and 3-Ni).",

keywords = "Catalytic activities, Coordination polymers, Metal coordination modes, Metal-benzoates, Transesterification",

author = "Kim, {Soo Hyun} and Park, {Byeong Kwon} and Song, {Young Joo} and Yu, {Seung Man} and Koo, {Hyo Geun} and Kim, {Eun Young} and Poong, {Jung In} and Lee, {Ju Hoon} and Cheal Kim and Kim, {Sung Jin} and Youngmee Kim",

note = "Funding Information: Financial support from Korea Ministry Environment “ET-Human resource development Project”, the Korea Research Foundation (2007-314-C00159), the Korean Science & Engineering Foundation (R01-2008-000-20704-0), The SEOUL R&BD Program, and the SRC program of the Korea Science and Engineering Foundation (KOSEF) through the Center for Intelligent Nano-Bio Materials at Ewha Womans University (Grant R11-2005-008-00000-0) is gratefully acknowledged. ",

year = "2009",

month = aug,

day = "15",

doi = "10.1016/j.ica.2009.06.008",

language = "English",

volume = "362",

pages = "4119--4126",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

number = "11",

}

Kim, SH, Park, BK, Song, YJ, Yu, SM, Koo, HG, Kim, EY, Poong, JI, Lee, JH, Kim, C, Kim, SJ & Kim, Y 2009, 'Construction of crystal structures of metal(II)-benzoates (M = Mn, Ni, Co, Cu, Zn, and Cd) and 1,2-bis(4-pyridyl)ethane: Effects of metal coordination modes and their catalytic activities', Inorganica Chimica Acta, vol. 362, no. 11, pp. 4119-4126. https://doi.org/10.1016/j.ica.2009.06.008

Construction of crystal structures of metal(II)-benzoates (M = Mn, Ni, Co, Cu, Zn, and Cd) and 1,2-bis(4-pyridyl)ethane: Effects of metal coordination modes and their catalytic activities. / Kim, Soo Hyun; Park, Byeong Kwon; Song, Young Joo et al.
In: Inorganica Chimica Acta, Vol. 362, No. 11, 15.08.2009, p. 4119-4126.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Construction of crystal structures of metal(II)-benzoates (M = Mn, Ni, Co, Cu, Zn, and Cd) and 1,2-bis(4-pyridyl)ethane

T2 - Effects of metal coordination modes and their catalytic activities

AU - Kim, Soo Hyun

AU - Park, Byeong Kwon

AU - Song, Young Joo

AU - Yu, Seung Man

AU - Koo, Hyo Geun

AU - Kim, Eun Young

AU - Poong, Jung In

AU - Lee, Ju Hoon

AU - Kim, Cheal

AU - Kim, Sung Jin

AU - Kim, Youngmee

N1 - Funding Information: Financial support from Korea Ministry Environment “ET-Human resource development Project”, the Korea Research Foundation (2007-314-C00159), the Korean Science & Engineering Foundation (R01-2008-000-20704-0), The SEOUL R&BD Program, and the SRC program of the Korea Science and Engineering Foundation (KOSEF) through the Center for Intelligent Nano-Bio Materials at Ewha Womans University (Grant R11-2005-008-00000-0) is gratefully acknowledged.

PY - 2009/8/15

Y1 - 2009/8/15

N2 - Five polymeric metal(II)-benzoate complexes of formula [Mn(O2CPh)2(CH3OH)2(bpa)]n (1-Mn), [Co(O2CPh)2(H2O)(bpa)1.5]n (2-Co), [Ni(O2CPh)2(H2O)(bpa)1.5]n (3-Ni), [Cu(O2CPh)2(CH3OH)2(bpa)]n (4-Cu), and [Cd(O2CPh)2(bpa)1.5]n (6-Cd) have been synthesized and characterized (bpa = 1,2-bis(4-pyridyl)ethane). They showed two kinds of structures: parallelogram-like two-dimensional sheets for Co, Ni, and Cd, and one-dimensional chains for Mn, Cu, and Zn. Since similar structures provide similar coordination geometries, the structures depend on the coordination geometries of metal ions. The compounds 1-Mn, 2-Co, 4-Cu, 5-Zn, and 6-Cd have catalyzed efficiently the transesterification of a variety of esters, while 3-Ni has displayed a very slow conversion. The reactivity of catalyst 6-Cd containing Cd ion, well known as an inert metal ion for the ligand substitution, was found to be comparable to that of 5-Zn. The reactivities of the compounds used in this study are in the order of 5-Zn > 6-Cd > 1-Mn > 4-Cu > 2-Co ≫ 3-Ni, indicating that the non-redox metal-containing compounds (5-Zn and 6-Cd) show better activity than the redox-active metal-containing compounds (1-Mn, 4-Cu, 2-Co, and 3-Ni).

AB - Five polymeric metal(II)-benzoate complexes of formula [Mn(O2CPh)2(CH3OH)2(bpa)]n (1-Mn), [Co(O2CPh)2(H2O)(bpa)1.5]n (2-Co), [Ni(O2CPh)2(H2O)(bpa)1.5]n (3-Ni), [Cu(O2CPh)2(CH3OH)2(bpa)]n (4-Cu), and [Cd(O2CPh)2(bpa)1.5]n (6-Cd) have been synthesized and characterized (bpa = 1,2-bis(4-pyridyl)ethane). They showed two kinds of structures: parallelogram-like two-dimensional sheets for Co, Ni, and Cd, and one-dimensional chains for Mn, Cu, and Zn. Since similar structures provide similar coordination geometries, the structures depend on the coordination geometries of metal ions. The compounds 1-Mn, 2-Co, 4-Cu, 5-Zn, and 6-Cd have catalyzed efficiently the transesterification of a variety of esters, while 3-Ni has displayed a very slow conversion. The reactivity of catalyst 6-Cd containing Cd ion, well known as an inert metal ion for the ligand substitution, was found to be comparable to that of 5-Zn. The reactivities of the compounds used in this study are in the order of 5-Zn > 6-Cd > 1-Mn > 4-Cu > 2-Co ≫ 3-Ni, indicating that the non-redox metal-containing compounds (5-Zn and 6-Cd) show better activity than the redox-active metal-containing compounds (1-Mn, 4-Cu, 2-Co, and 3-Ni).

KW - Catalytic activities

KW - Coordination polymers

KW - Metal coordination modes

KW - Metal-benzoates

KW - Transesterification

UR - http://www.scopus.com/inward/record.url?scp=67849088518&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2009.06.008

DO - 10.1016/j.ica.2009.06.008

M3 - Article

AN - SCOPUS:67849088518

SN - 0020-1693

VL - 362

SP - 4119

EP - 4126

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 11

ER -

Construction of crystal structures of metal(II)-benzoates (M = Mn, Ni, Co, Cu, Zn, and Cd) and 1,2-bis(4-pyridyl)ethane: Effects of metal coordination modes and their catalytic activities

Abstract

Bibliographical note

Keywords

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