Comparison of reorganization energies for intra- and intermolecular electron transfer

Hiroshi Imahori; Hiroko Yamada; Dirk M. Guldi; Yoshito Endo; Akihisa Shimomura; Santi Kundu; Koji Yamada; Tadashi Okada; Yoshiteru Sakata; Shunichi Fukuzumi

doi:10.1002/1521-3773(20020703)41:13<2344::AID-ANIE2344>3.0.CO;2-7

Comparison of reorganization energies for intra- and intermolecular electron transfer

Hiroshi Imahori, Hiroko Yamada, Dirk M. Guldi, Yoshito Endo, Akihisa Shimomura, Santi Kundu, Koji Yamada, Tadashi Okada, Yoshiteru Sakata, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

196 Scopus citations

Abstract

Do electrons prefer to visit planes or spheres? Reorganization energies for intramolecular electron transfer involving a 3D acceptor (C₆₀) and a 2D acceptor (NIm; see scheme) have been determined. Comparison of reorganization energies for the intra- versus intermolecular electron transfer has provided, for the first time, valuable insight into the intrinsic reorganization energies relating to different molecular shapes.

Original language	English
Pages (from-to)	2344-2347
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	13
DOIs	https://doi.org/10.1002/1521-3773(20020703)41:13<2344::AID-ANIE2344>3.0.CO;2-7
State	Published - 2 Jul 2002

Keywords

Donor-acceptor systems
Electron transfer
Fullerenes
Photosynthesis
Porphyrinoids

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10.1002/1521-3773(20020703)41:13<2344::AID-ANIE2344>3.0.CO;2-7

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T1 - Comparison of reorganization energies for intra- and intermolecular electron transfer

AU - Imahori, Hiroshi

AU - Yamada, Hiroko

AU - Guldi, Dirk M.

AU - Endo, Yoshito

AU - Shimomura, Akihisa

AU - Kundu, Santi

AU - Yamada, Koji

AU - Okada, Tadashi

AU - Sakata, Yoshiteru

AU - Fukuzumi, Shunichi

PY - 2002/7/2

Y1 - 2002/7/2

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AB - Do electrons prefer to visit planes or spheres? Reorganization energies for intramolecular electron transfer involving a 3D acceptor (C60) and a 2D acceptor (NIm; see scheme) have been determined. Comparison of reorganization energies for the intra- versus intermolecular electron transfer has provided, for the first time, valuable insight into the intrinsic reorganization energies relating to different molecular shapes.

KW - Donor-acceptor systems

KW - Electron transfer

KW - Fullerenes

KW - Photosynthesis

KW - Porphyrinoids

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JF - Angewandte Chemie - International Edition

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Comparison of reorganization energies for intra- and intermolecular electron transfer

Abstract

Keywords

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