Colorimetric Detection of Thiophenol Based on a Phenolphthalein Derivative and Its Application as a Molecular Logic Gate

Hyunsu Kim; K. M.K. Swamy; Nahyun Kwon; Yonghee Kim; Sungsu Park; Juyoung Yoon

doi:10.1002/cphc.201601348

Colorimetric Detection of Thiophenol Based on a Phenolphthalein Derivative and Its Application as a Molecular Logic Gate

Hyunsu Kim, K. M.K. Swamy, Nahyun Kwon, Yonghee Kim, Sungsu Park, Juyoung Yoon

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

A phenolphthalein-based colorimetric probe bearing a dinitrobenzene group is reported as a thiophenol (PhSH)-selective chemodosimeter. PhSH can react with chemodosimeter 1 to afford phenolphthalein. The addition of PhSH to the aqueous solution of 1 followed by a change in pH of the resulting solution to basic induces a selective color change from colorless to pink. Furthermore, using PhSH and base as inputs and color change of 1 by naked eye as an output, leads to the construction of an AND logic gate.

Original language	English
Pages (from-to)	1752-1754
Number of pages	3
Journal	ChemPhysChem
Volume	18
Issue number	13
DOIs	https://doi.org/10.1002/cphc.201601348
State	Published - 5 Jul 2017

Bibliographical note

Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Keywords

chemodosimeter
colorimetric sensor
molecular logic gate
phenolphthalein
thiophenol detection

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10.1002/cphc.201601348

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title = "Colorimetric Detection of Thiophenol Based on a Phenolphthalein Derivative and Its Application as a Molecular Logic Gate",

abstract = "A phenolphthalein-based colorimetric probe bearing a dinitrobenzene group is reported as a thiophenol (PhSH)-selective chemodosimeter. PhSH can react with chemodosimeter 1 to afford phenolphthalein. The addition of PhSH to the aqueous solution of 1 followed by a change in pH of the resulting solution to basic induces a selective color change from colorless to pink. Furthermore, using PhSH and base as inputs and color change of 1 by naked eye as an output, leads to the construction of an AND logic gate.",

keywords = "chemodosimeter, colorimetric sensor, molecular logic gate, phenolphthalein, thiophenol detection",

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note = "Publisher Copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

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T1 - Colorimetric Detection of Thiophenol Based on a Phenolphthalein Derivative and Its Application as a Molecular Logic Gate

AU - Kim, Hyunsu

AU - Swamy, K. M.K.

AU - Kwon, Nahyun

AU - Kim, Yonghee

AU - Park, Sungsu

AU - Yoon, Juyoung

PY - 2017/7/5

Y1 - 2017/7/5

N2 - A phenolphthalein-based colorimetric probe bearing a dinitrobenzene group is reported as a thiophenol (PhSH)-selective chemodosimeter. PhSH can react with chemodosimeter 1 to afford phenolphthalein. The addition of PhSH to the aqueous solution of 1 followed by a change in pH of the resulting solution to basic induces a selective color change from colorless to pink. Furthermore, using PhSH and base as inputs and color change of 1 by naked eye as an output, leads to the construction of an AND logic gate.

AB - A phenolphthalein-based colorimetric probe bearing a dinitrobenzene group is reported as a thiophenol (PhSH)-selective chemodosimeter. PhSH can react with chemodosimeter 1 to afford phenolphthalein. The addition of PhSH to the aqueous solution of 1 followed by a change in pH of the resulting solution to basic induces a selective color change from colorless to pink. Furthermore, using PhSH and base as inputs and color change of 1 by naked eye as an output, leads to the construction of an AND logic gate.

KW - chemodosimeter

KW - colorimetric sensor

KW - molecular logic gate

KW - phenolphthalein

KW - thiophenol detection

UR - https://www.scopus.com/pages/publications/85013288128

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DO - 10.1002/cphc.201601348

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JO - ChemPhysChem

JF - ChemPhysChem

IS - 13

ER -

Colorimetric Detection of Thiophenol Based on a Phenolphthalein Derivative and Its Application as a Molecular Logic Gate

Abstract

Bibliographical note

Keywords

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