Colorimetric and fluorescent sensing of pyrophosphate in 100% aqueous solution by a system comprised of rhodamine B compound and Al3+ complex

Chuda Raj Lohani; Joung Min Kim; So Young Chung; Juyoung Yoon; Keun Hyeung Lee

doi:10.1039/c0an00059k

Colorimetric and fluorescent sensing of pyrophosphate in 100% aqueous solution by a system comprised of rhodamine B compound and Al³⁺ complex

Chuda Raj Lohani, Joung Min Kim, So Young Chung, Juyoung Yoon, Keun Hyeung Lee

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

234 Scopus citations

Abstract

We developed a simple dual signal (color and 'Off-On' fluorescent change) ensemble system based on the complex between a rhodamine derivative 1 and Al³⁺ for the detection of pyrophosphate (PPi) in 100% aqueous solutions. The complex between the rhodamine compound and Al³⁺ was utilized as a chemosensing ensemble for the first time. The ensemble showed highly sensitive and selective fluorescent and colorimetric response to pyrophosphate among the anions in 100% aqueous solutions and no interference of the potent biological competitors including ATP, ADP, and phosphate for the detection of PPi in 100% aqueous solutions at pH 7.4.

Original language	English
Pages (from-to)	2079-2084
Number of pages	6
Journal	Analyst
Volume	135
Issue number	8
DOIs	https://doi.org/10.1039/c0an00059k
State	Published - Aug 2010

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abstract = "We developed a simple dual signal (color and 'Off-On' fluorescent change) ensemble system based on the complex between a rhodamine derivative 1 and Al3+ for the detection of pyrophosphate (PPi) in 100% aqueous solutions. The complex between the rhodamine compound and Al3+ was utilized as a chemosensing ensemble for the first time. The ensemble showed highly sensitive and selective fluorescent and colorimetric response to pyrophosphate among the anions in 100% aqueous solutions and no interference of the potent biological competitors including ATP, ADP, and phosphate for the detection of PPi in 100% aqueous solutions at pH 7.4.",

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AU - Lohani, Chuda Raj

AU - Kim, Joung Min

AU - Chung, So Young

AU - Yoon, Juyoung

AU - Lee, Keun Hyeung

PY - 2010/8

Y1 - 2010/8

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AB - We developed a simple dual signal (color and 'Off-On' fluorescent change) ensemble system based on the complex between a rhodamine derivative 1 and Al3+ for the detection of pyrophosphate (PPi) in 100% aqueous solutions. The complex between the rhodamine compound and Al3+ was utilized as a chemosensing ensemble for the first time. The ensemble showed highly sensitive and selective fluorescent and colorimetric response to pyrophosphate among the anions in 100% aqueous solutions and no interference of the potent biological competitors including ATP, ADP, and phosphate for the detection of PPi in 100% aqueous solutions at pH 7.4.

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JO - Analyst

JF - Analyst

IS - 8

ER -

Colorimetric and fluorescent sensing of pyrophosphate in 100% aqueous solution by a system comprised of rhodamine B compound and Al3+ complex

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Colorimetric and fluorescent sensing of pyrophosphate in 100% aqueous solution by a system comprised of rhodamine B compound and Al³⁺ complex