Chiral binaphthyl receptors bearing imidazolium or urea groups for the recognition of anions

K. M.K. Swamy; N. Jiten Singh; Jaeduk Yoo; Soo Kyung Kwon; So Young Chung; Chang Hee Lee; Juyoung Yoon

doi:10.1007/s10847-009-9658-y

Chiral binaphthyl receptors bearing imidazolium or urea groups for the recognition of anions

K. M.K. Swamy, N. Jiten Singh, Jaeduk Yoo, Soo Kyung Kwon, So Young Chung, Chang Hee Lee, Juyoung Yoon

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Two new binaphthyl derivatives 1 and 2 bearing two imidazolium, or bisurea groups were investigated as fluorescent chemosensors for the chiral anion recognition. Receptors 1 and 2 displayed a better selectivity for (S)-2-phenylbutylate over (R)-2-phenylbutylate. Isothermal titration calorimeter methods, fluorescence as well as theoretical calculations are utilized to explain chiral selectivity.

Original language	English
Pages (from-to)	107-111
Number of pages	5
Journal	Journal of Inclusion Phenomena
Volume	66
Issue number	1
DOIs	https://doi.org/10.1007/s10847-009-9658-y
State	Published - Jan 2010

Bibliographical note

Funding Information:
Acknowledgements This work was supported by grants from KOSEF/MEST (SRC; R11-2005-008-02003-0) and collaboration fund between Korea and China (KOSEF; F01-2008-000-10026-0, Chinese NSFC; 50811140342). Authors also thank to Professor K. S. Kim and He Tian for helpful discussion. J.Y., S.K.K. and S-Y.C. thank to BK 21 fellowship. We also thank KBSI in Daegu, Korea, for their instrumentation assistance (FAB mass spectra).

Keywords

Binaphthyl imidazolium
Chiral anion recognition
Fluorescent chemosensors
Host-guest interaction

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title = "Chiral binaphthyl receptors bearing imidazolium or urea groups for the recognition of anions",

abstract = "Two new binaphthyl derivatives 1 and 2 bearing two imidazolium, or bisurea groups were investigated as fluorescent chemosensors for the chiral anion recognition. Receptors 1 and 2 displayed a better selectivity for (S)-2-phenylbutylate over (R)-2-phenylbutylate. Isothermal titration calorimeter methods, fluorescence as well as theoretical calculations are utilized to explain chiral selectivity.",

keywords = "Binaphthyl imidazolium, Chiral anion recognition, Fluorescent chemosensors, Host-guest interaction",

author = "Swamy, {K. M.K.} and Singh, {N. Jiten} and Jaeduk Yoo and Kwon, {Soo Kyung} and Chung, {So Young} and Lee, {Chang Hee} and Juyoung Yoon",

note = "Funding Information: Acknowledgements This work was supported by grants from KOSEF/MEST (SRC; R11-2005-008-02003-0) and collaboration fund between Korea and China (KOSEF; F01-2008-000-10026-0, Chinese NSFC; 50811140342). Authors also thank to Professor K. S. Kim and He Tian for helpful discussion. J.Y., S.K.K. and S-Y.C. thank to BK 21 fellowship. We also thank KBSI in Daegu, Korea, for their instrumentation assistance (FAB mass spectra).",

year = "2010",

month = jan,

doi = "10.1007/s10847-009-9658-y",

language = "English",

volume = "66",

pages = "107--111",

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AU - Singh, N. Jiten

AU - Yoo, Jaeduk

AU - Kwon, Soo Kyung

AU - Chung, So Young

AU - Lee, Chang Hee

AU - Yoon, Juyoung

N1 - Funding Information: Acknowledgements This work was supported by grants from KOSEF/MEST (SRC; R11-2005-008-02003-0) and collaboration fund between Korea and China (KOSEF; F01-2008-000-10026-0, Chinese NSFC; 50811140342). Authors also thank to Professor K. S. Kim and He Tian for helpful discussion. J.Y., S.K.K. and S-Y.C. thank to BK 21 fellowship. We also thank KBSI in Daegu, Korea, for their instrumentation assistance (FAB mass spectra).

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KW - Binaphthyl imidazolium

KW - Chiral anion recognition

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KW - Host-guest interaction

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Chiral binaphthyl receptors bearing imidazolium or urea groups for the recognition of anions

Abstract

Bibliographical note

Keywords

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