Charge-Transfer Spectra of Permethylated Polygermanes—TCNE To Afford 1:1 Adducts

Kunio Mochida; Chikako Hodota; Rieko Hata; Shunichi Fukuzumi

doi:10.1021/om00026a052

Charge-Transfer Spectra of Permethylated Polygermanes—TCNE To Afford 1:1 Adducts

Kunio Mochida, Chikako Hodota, Rieko Hata, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Comment/debate

46 Scopus citations

Abstract

Charge-transfer spectra of permethylated polygermane—tetracyanoethylene (TCNE) complexes were observed. The frequency of charge-transfer spectra was linearly related to ionization potentials (or electrochemical oxidation potentials) of the polygermanes. Polygermanes inserted into TCNE to afford 1:1 adducts under mild conditions.

Original language	English
Pages (from-to)	586-588
Number of pages	3
Journal	Organometallics
Volume	12
Issue number	2
DOIs	https://doi.org/10.1021/om00026a052
State	Published - 1993

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@article{75fa0be087314e308dca3ac4628559fc,

title = "Charge-Transfer Spectra of Permethylated Polygermanes—TCNE To Afford 1:1 Adducts",

abstract = "Charge-transfer spectra of permethylated polygermane—tetracyanoethylene (TCNE) complexes were observed. The frequency of charge-transfer spectra was linearly related to ionization potentials (or electrochemical oxidation potentials) of the polygermanes. Polygermanes inserted into TCNE to afford 1:1 adducts under mild conditions.",

author = "Kunio Mochida and Chikako Hodota and Rieko Hata and Shunichi Fukuzumi",

year = "1993",

doi = "10.1021/om00026a052",

language = "English",

volume = "12",

pages = "586--588",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "2",

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T1 - Charge-Transfer Spectra of Permethylated Polygermanes—TCNE To Afford 1:1 Adducts

AU - Mochida, Kunio

AU - Hodota, Chikako

AU - Hata, Rieko

AU - Fukuzumi, Shunichi

PY - 1993

Y1 - 1993

N2 - Charge-transfer spectra of permethylated polygermane—tetracyanoethylene (TCNE) complexes were observed. The frequency of charge-transfer spectra was linearly related to ionization potentials (or electrochemical oxidation potentials) of the polygermanes. Polygermanes inserted into TCNE to afford 1:1 adducts under mild conditions.

AB - Charge-transfer spectra of permethylated polygermane—tetracyanoethylene (TCNE) complexes were observed. The frequency of charge-transfer spectra was linearly related to ionization potentials (or electrochemical oxidation potentials) of the polygermanes. Polygermanes inserted into TCNE to afford 1:1 adducts under mild conditions.

UR - http://www.scopus.com/inward/record.url?scp=0001668599&partnerID=8YFLogxK

U2 - 10.1021/om00026a052

DO - 10.1021/om00026a052

M3 - Comment/debate

AN - SCOPUS:0001668599

SN - 0276-7333

VL - 12

SP - 586

EP - 588

JO - Organometallics

JF - Organometallics

IS - 2

ER -

Charge-Transfer Spectra of Permethylated Polygermanes—TCNE To Afford 1:1 Adducts

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