Characterization of imidazolate-bridged Cu(II)-Zn(II) heterodinuclear and Cu(II)-Cu(II) homodinuclear hydroperoxo complexes as reaction intermediate models of Cu,Zn-SOD

Hideki Ohtsu; Shinobu Itoh; Shigenori Nagatomo; Teizo Kitagawa; Seiji Ogo; Yoshihito Watanabe; Shunichi Fukuzumi

doi:10.1039/b002208j

Characterization of imidazolate-bridged Cu(II)-Zn(II) heterodinuclear and Cu(II)-Cu(II) homodinuclear hydroperoxo complexes as reaction intermediate models of Cu,Zn-SOD

Hideki Ohtsu, Shinobu Itoh, Shigenori Nagatomo, Teizo Kitagawa, Seiji Ogo, Yoshihito Watanabe, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

Imidazolate-bridged Cu(II)-Zn(II) heterodinuclear and Cu(II)-Cu(II) homodinuclear hydroperoxo complexes are generated in the reactions between imidazolate-bridged heterodinuclear and homodinuclear complexes and H₂O₂ in the presence of triethylamine base and characterized spectroscopically as reaction intermediate models of Cu,Zn-SOD.

Original language	English
Pages (from-to)	1051-1052
Number of pages	2
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/b002208j
State	Published - 21 Jun 2000

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title = "Characterization of imidazolate-bridged Cu(II)-Zn(II) heterodinuclear and Cu(II)-Cu(II) homodinuclear hydroperoxo complexes as reaction intermediate models of Cu,Zn-SOD",

abstract = "Imidazolate-bridged Cu(II)-Zn(II) heterodinuclear and Cu(II)-Cu(II) homodinuclear hydroperoxo complexes are generated in the reactions between imidazolate-bridged heterodinuclear and homodinuclear complexes and H2O2 in the presence of triethylamine base and characterized spectroscopically as reaction intermediate models of Cu,Zn-SOD.",

author = "Hideki Ohtsu and Shinobu Itoh and Shigenori Nagatomo and Teizo Kitagawa and Seiji Ogo and Yoshihito Watanabe and Shunichi Fukuzumi",

year = "2000",

month = jun,

day = "21",

doi = "10.1039/b002208j",

language = "English",

pages = "1051--1052",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Characterization of imidazolate-bridged Cu(II)-Zn(II) heterodinuclear and Cu(II)-Cu(II) homodinuclear hydroperoxo complexes as reaction intermediate models of Cu,Zn-SOD

AU - Ohtsu, Hideki

AU - Itoh, Shinobu

AU - Nagatomo, Shigenori

AU - Kitagawa, Teizo

AU - Ogo, Seiji

AU - Watanabe, Yoshihito

AU - Fukuzumi, Shunichi

PY - 2000/6/21

Y1 - 2000/6/21

N2 - Imidazolate-bridged Cu(II)-Zn(II) heterodinuclear and Cu(II)-Cu(II) homodinuclear hydroperoxo complexes are generated in the reactions between imidazolate-bridged heterodinuclear and homodinuclear complexes and H2O2 in the presence of triethylamine base and characterized spectroscopically as reaction intermediate models of Cu,Zn-SOD.

AB - Imidazolate-bridged Cu(II)-Zn(II) heterodinuclear and Cu(II)-Cu(II) homodinuclear hydroperoxo complexes are generated in the reactions between imidazolate-bridged heterodinuclear and homodinuclear complexes and H2O2 in the presence of triethylamine base and characterized spectroscopically as reaction intermediate models of Cu,Zn-SOD.

UR - http://www.scopus.com/inward/record.url?scp=0034697755&partnerID=8YFLogxK

U2 - 10.1039/b002208j

DO - 10.1039/b002208j

M3 - Article

AN - SCOPUS:0034697755

SN - 1359-7345

SP - 1051

EP - 1052

JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

Characterization of imidazolate-bridged Cu(II)-Zn(II) heterodinuclear and Cu(II)-Cu(II) homodinuclear hydroperoxo complexes as reaction intermediate models of Cu,Zn-SOD

Abstract

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