CdII MOFs constructed using succinate and bipyridyl ligands: Photoluminescence and heterogeneous catalytic activity

Myoung Mi Lee; Ha Yeong Kim; In Hong Hwang; Jeong Mi Bae; Cheal Kim; Chul Hyun Yo; Youngmee Kim; Sung Jin Kim

doi:10.5012/bkcs.2014.35.6.1777

Cd^II MOFs constructed using succinate and bipyridyl ligands: Photoluminescence and heterogeneous catalytic activity

Myoung Mi Lee, Ha Yeong Kim, In Hong Hwang, Jeong Mi Bae, Cheal Kim, Chul Hyun Yo, Youngmee Kim, Sung Jin Kim

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Four Cd^II MOFs, [Cd₂(μ-succinate) ₂(H₂O)₂]·H₂O (1A), [Cd ₂(μ-succinate)₂(μ-4,4′-bpy) ₂]·H₂O (1B), [{Cd₂(μ-succinate) ₂}(μ-bpa)₂{Cd(H₂O)₂}(NO ₃)2]·H₂O (2), and [Cd(μ-succinate)(μ-bpp) ₂]·2H₂O (3), with various bipyridyl ligands (4,4′-bipyridine (4,4′-bpy), 1,2-bis(4-pyridyl)ethane (bpa), and 1,3-bis(4-pyridyl)propane (bpp)) were prepared, and their structures were determined using X-ray crystallography. The structures and dimensionalities of Cd^II-(succinate) compounds varied depending on the auxiliary ligands. Heterogeneous catalytic activity for transesterification reactions, photoluminescence and the thermal stabilities of these compounds were also examined.

Original language	English
Pages (from-to)	1777-1783
Number of pages	7
Journal	Bulletin of the Korean Chemical Society
Volume	35
Issue number	6
DOIs	https://doi.org/10.5012/bkcs.2014.35.6.1777
State	Published - 20 Jun 2014

Keywords

Heterogeneous catalysts
Photoluminescence
Succinate
Transesterification

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10.5012/bkcs.2014.35.6.1777

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@article{97bdc410789f48b39b7f18eff1ff1e74,

title = "CdII MOFs constructed using succinate and bipyridyl ligands: Photoluminescence and heterogeneous catalytic activity",

abstract = "Four CdII MOFs, [Cd2(μ-succinate) 2(H2O)2]·H2O (1A), [Cd 2(μ-succinate)2(μ-4,4′-bpy) 2]·H2O (1B), [{Cd2(μ-succinate) 2}(μ-bpa)2{Cd(H2O)2}(NO 3)2]·H2O (2), and [Cd(μ-succinate)(μ-bpp) 2]·2H2O (3), with various bipyridyl ligands (4,4′-bipyridine (4,4′-bpy), 1,2-bis(4-pyridyl)ethane (bpa), and 1,3-bis(4-pyridyl)propane (bpp)) were prepared, and their structures were determined using X-ray crystallography. The structures and dimensionalities of CdII-(succinate) compounds varied depending on the auxiliary ligands. Heterogeneous catalytic activity for transesterification reactions, photoluminescence and the thermal stabilities of these compounds were also examined.",

keywords = "Heterogeneous catalysts, Photoluminescence, Succinate, Transesterification",

author = "Lee, {Myoung Mi} and Kim, {Ha Yeong} and Hwang, {In Hong} and Bae, {Jeong Mi} and Cheal Kim and Yo, {Chul Hyun} and Youngmee Kim and Kim, {Sung Jin}",

year = "2014",

month = jun,

day = "20",

doi = "10.5012/bkcs.2014.35.6.1777",

language = "English",

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T1 - CdII MOFs constructed using succinate and bipyridyl ligands

T2 - Photoluminescence and heterogeneous catalytic activity

AU - Lee, Myoung Mi

AU - Kim, Ha Yeong

AU - Hwang, In Hong

AU - Bae, Jeong Mi

AU - Kim, Cheal

AU - Yo, Chul Hyun

AU - Kim, Youngmee

AU - Kim, Sung Jin

PY - 2014/6/20

Y1 - 2014/6/20

N2 - Four CdII MOFs, [Cd2(μ-succinate) 2(H2O)2]·H2O (1A), [Cd 2(μ-succinate)2(μ-4,4′-bpy) 2]·H2O (1B), [{Cd2(μ-succinate) 2}(μ-bpa)2{Cd(H2O)2}(NO 3)2]·H2O (2), and [Cd(μ-succinate)(μ-bpp) 2]·2H2O (3), with various bipyridyl ligands (4,4′-bipyridine (4,4′-bpy), 1,2-bis(4-pyridyl)ethane (bpa), and 1,3-bis(4-pyridyl)propane (bpp)) were prepared, and their structures were determined using X-ray crystallography. The structures and dimensionalities of CdII-(succinate) compounds varied depending on the auxiliary ligands. Heterogeneous catalytic activity for transesterification reactions, photoluminescence and the thermal stabilities of these compounds were also examined.

AB - Four CdII MOFs, [Cd2(μ-succinate) 2(H2O)2]·H2O (1A), [Cd 2(μ-succinate)2(μ-4,4′-bpy) 2]·H2O (1B), [{Cd2(μ-succinate) 2}(μ-bpa)2{Cd(H2O)2}(NO 3)2]·H2O (2), and [Cd(μ-succinate)(μ-bpp) 2]·2H2O (3), with various bipyridyl ligands (4,4′-bipyridine (4,4′-bpy), 1,2-bis(4-pyridyl)ethane (bpa), and 1,3-bis(4-pyridyl)propane (bpp)) were prepared, and their structures were determined using X-ray crystallography. The structures and dimensionalities of CdII-(succinate) compounds varied depending on the auxiliary ligands. Heterogeneous catalytic activity for transesterification reactions, photoluminescence and the thermal stabilities of these compounds were also examined.

KW - Heterogeneous catalysts

KW - Photoluminescence

KW - Succinate

KW - Transesterification

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