CdII MOFs constructed using succinate and bipyridyl ligands: Photoluminescence and heterogeneous catalytic activity

Myoung Mi Lee, Ha Yeong Kim, In Hong Hwang, Jeong Mi Bae, Cheal Kim, Chul Hyun Yo, Youngmee Kim, Sung Jin Kim

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

Four CdII MOFs, [Cd2(μ-succinate) 2(H2O)2]·H2O (1A), [Cd 2(μ-succinate)2(μ-4,4′-bpy) 2]·H2O (1B), [{Cd2(μ-succinate) 2}(μ-bpa)2{Cd(H2O)2}(NO 3)2]·H2O (2), and [Cd(μ-succinate)(μ-bpp) 2]·2H2O (3), with various bipyridyl ligands (4,4′-bipyridine (4,4′-bpy), 1,2-bis(4-pyridyl)ethane (bpa), and 1,3-bis(4-pyridyl)propane (bpp)) were prepared, and their structures were determined using X-ray crystallography. The structures and dimensionalities of CdII-(succinate) compounds varied depending on the auxiliary ligands. Heterogeneous catalytic activity for transesterification reactions, photoluminescence and the thermal stabilities of these compounds were also examined.

Original languageEnglish
Pages (from-to)1777-1783
Number of pages7
JournalBulletin of the Korean Chemical Society
Volume35
Issue number6
DOIs
StatePublished - 20 Jun 2014

Keywords

  • Heterogeneous catalysts
  • Photoluminescence
  • Succinate
  • Transesterification

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