Catalytic oxidation of formic acid by dioxygen with an organoiridium complex

Tomoyoshi Suenobu; Satoshi Shibata; Shunichi Fukuzumi

doi:10.1039/c4cy00957f

Catalytic oxidation of formic acid by dioxygen with an organoiridium complex

Tomoyoshi Suenobu
, Satoshi Shibata
, Shunichi Fukuzumi

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Catalytic oxidation of formic acid by dioxygen occurred efficiently using an organoiridium complex ([Ir^III(Cp^∗)(4-(1H-pyrazol-1-yl-κN²)benzoic acid-κC³)(H₂O)]₂SO₄, 1) as a catalyst in a water-containing organic solvent as well as in water at ambient temperature. The catalytic cycle is composed of the reduction of 1 by formate to produce the hydride complex, which reduces dioxygen to water to regenerate 1.

Original language	English
Pages (from-to)	3636-3639
Number of pages	4
Journal	Catalysis Science and Technology
Volume	4
Issue number	10
DOIs	https://doi.org/10.1039/c4cy00957f
State	Published - 1 Oct 2014

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© the Partner Organisations 2014.

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title = "Catalytic oxidation of formic acid by dioxygen with an organoiridium complex",

abstract = "Catalytic oxidation of formic acid by dioxygen occurred efficiently using an organoiridium complex ([IrIII(Cp∗)(4-(1H-pyrazol-1-yl-κN2)benzoic acid-κC3)(H2O)]2SO4, 1) as a catalyst in a water-containing organic solvent as well as in water at ambient temperature. The catalytic cycle is composed of the reduction of 1 by formate to produce the hydride complex, which reduces dioxygen to water to regenerate 1.",

author = "Tomoyoshi Suenobu and Satoshi Shibata and Shunichi Fukuzumi",

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doi = "10.1039/c4cy00957f",

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AU - Suenobu, Tomoyoshi

AU - Shibata, Satoshi

AU - Fukuzumi, Shunichi

PY - 2014/10/1

Y1 - 2014/10/1

N2 - Catalytic oxidation of formic acid by dioxygen occurred efficiently using an organoiridium complex ([IrIII(Cp∗)(4-(1H-pyrazol-1-yl-κN2)benzoic acid-κC3)(H2O)]2SO4, 1) as a catalyst in a water-containing organic solvent as well as in water at ambient temperature. The catalytic cycle is composed of the reduction of 1 by formate to produce the hydride complex, which reduces dioxygen to water to regenerate 1.

AB - Catalytic oxidation of formic acid by dioxygen occurred efficiently using an organoiridium complex ([IrIII(Cp∗)(4-(1H-pyrazol-1-yl-κN2)benzoic acid-κC3)(H2O)]2SO4, 1) as a catalyst in a water-containing organic solvent as well as in water at ambient temperature. The catalytic cycle is composed of the reduction of 1 by formate to produce the hydride complex, which reduces dioxygen to water to regenerate 1.

UR - https://www.scopus.com/pages/publications/84907159727

U2 - 10.1039/c4cy00957f

DO - 10.1039/c4cy00957f

M3 - Article

AN - SCOPUS:84907159727

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SP - 3636

EP - 3639

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 10

ER -

Catalytic oxidation of formic acid by dioxygen with an organoiridium complex

Abstract

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