Catalytic oxidation of alkanes by iron bispidine complexes and dioxygen: Oxygen activation versus autoxidation

Peter Comba; Yong Min Lee; Wonwoo Nam; Arkadius Waleska

doi:10.1039/c3cc47013j

Catalytic oxidation of alkanes by iron bispidine complexes and dioxygen: Oxygen activation versus autoxidation

Peter Comba, Yong Min Lee, Wonwoo Nam, Arkadius Waleska

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

Organic substrates (specifically cis-1,2-dimethylcyclohexane, DMCH) are oxidized by O₂ in the presence of iron(ii)–bispidine complexes. It is shown that this oxidation reaction is not based on O₂ activation by the nonheme iron catalysts as in Nature but due to a radical-based initiation, followed by a radical- and ferryl-based catalytic reaction.

Original language	English
Pages (from-to)	412-414
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	4
DOIs	https://doi.org/10.1039/c3cc47013j
State	Published - 5 Dec 2014

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title = "Catalytic oxidation of alkanes by iron bispidine complexes and dioxygen: Oxygen activation versus autoxidation",

abstract = "Organic substrates (specifically cis-1,2-dimethylcyclohexane, DMCH) are oxidized by O2 in the presence of iron(ii)–bispidine complexes. It is shown that this oxidation reaction is not based on O2 activation by the nonheme iron catalysts as in Nature but due to a radical-based initiation, followed by a radical- and ferryl-based catalytic reaction.",

author = "Peter Comba and Lee, {Yong Min} and Wonwoo Nam and Arkadius Waleska",

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AU - Comba, Peter

AU - Lee, Yong Min

AU - Nam, Wonwoo

AU - Waleska, Arkadius

PY - 2014/12/5

Y1 - 2014/12/5

N2 - Organic substrates (specifically cis-1,2-dimethylcyclohexane, DMCH) are oxidized by O2 in the presence of iron(ii)–bispidine complexes. It is shown that this oxidation reaction is not based on O2 activation by the nonheme iron catalysts as in Nature but due to a radical-based initiation, followed by a radical- and ferryl-based catalytic reaction.

AB - Organic substrates (specifically cis-1,2-dimethylcyclohexane, DMCH) are oxidized by O2 in the presence of iron(ii)–bispidine complexes. It is shown that this oxidation reaction is not based on O2 activation by the nonheme iron catalysts as in Nature but due to a radical-based initiation, followed by a radical- and ferryl-based catalytic reaction.

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Catalytic oxidation of alkanes by iron bispidine complexes and dioxygen: Oxygen activation versus autoxidation

Abstract

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