Catalysis by magnesium ion of the reduction of oxygen by the 1,5-dihydroflavin anion via electron transfer

Shunichi Fukuzumi; Toshihiko Okamoto

doi:10.1039/C39940000521

Catalysis by magnesium ion of the reduction of oxygen by the 1,5-dihydroflavin anion via electron transfer

Shunichi Fukuzumi
, Toshihiko Okamoto

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Comparison of the catalytic effect of Mg²⁺ in reduction of O₂ by 1,5-dihydroflavin anion with that in electron transfer from decamethylferrocene to O₂ has revealed that the catalysis of Mg ²⁺ in both cases is ascribed to the 1: 1 and 1: 2 complexes formed between O₂^.- and Mg²⁺, which result in acceleration of the rate of electron-transfer reduction of O₂ to O₂^.- in MeCN.

Original language	English
Pages (from-to)	521-522
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39940000521
State	Published - 1994

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@article{2c5544498aca4802aab42976c27f3ce5,

title = "Catalysis by magnesium ion of the reduction of oxygen by the 1,5-dihydroflavin anion via electron transfer",

abstract = "Comparison of the catalytic effect of Mg2+ in reduction of O2 by 1,5-dihydroflavin anion with that in electron transfer from decamethylferrocene to O2 has revealed that the catalysis of Mg 2+ in both cases is ascribed to the 1: 1 and 1: 2 complexes formed between O2.- and Mg2+, which result in acceleration of the rate of electron-transfer reduction of O2 to O2.- in MeCN.",

author = "Shunichi Fukuzumi and Toshihiko Okamoto",

year = "1994",

doi = "10.1039/C39940000521",

language = "English",

pages = "521--522",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "4",

}

TY - JOUR

T1 - Catalysis by magnesium ion of the reduction of oxygen by the 1,5-dihydroflavin anion via electron transfer

AU - Fukuzumi, Shunichi

AU - Okamoto, Toshihiko

PY - 1994

Y1 - 1994

N2 - Comparison of the catalytic effect of Mg2+ in reduction of O2 by 1,5-dihydroflavin anion with that in electron transfer from decamethylferrocene to O2 has revealed that the catalysis of Mg 2+ in both cases is ascribed to the 1: 1 and 1: 2 complexes formed between O2.- and Mg2+, which result in acceleration of the rate of electron-transfer reduction of O2 to O2.- in MeCN.

AB - Comparison of the catalytic effect of Mg2+ in reduction of O2 by 1,5-dihydroflavin anion with that in electron transfer from decamethylferrocene to O2 has revealed that the catalysis of Mg 2+ in both cases is ascribed to the 1: 1 and 1: 2 complexes formed between O2.- and Mg2+, which result in acceleration of the rate of electron-transfer reduction of O2 to O2.- in MeCN.

UR - https://www.scopus.com/pages/publications/37049089634

U2 - 10.1039/C39940000521

DO - 10.1039/C39940000521

M3 - Article

AN - SCOPUS:37049089634

SN - 0022-4936

SP - 521

EP - 522

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 4

ER -

Catalysis by magnesium ion of the reduction of oxygen by the 1,5-dihydroflavin anion via electron transfer

Abstract

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