TY - JOUR
T1 - Catalysis by magnesium ion of the reduction of oxygen by the 1,5-dihydroflavin anion via electron transfer
AU - Fukuzumi, Shunichi
AU - Okamoto, Toshihiko
PY - 1994
Y1 - 1994
N2 - Comparison of the catalytic effect of Mg2+ in reduction of O2 by 1,5-dihydroflavin anion with that in electron transfer from decamethylferrocene to O2 has revealed that the catalysis of Mg 2+ in both cases is ascribed to the 1: 1 and 1: 2 complexes formed between O2.- and Mg2+, which result in acceleration of the rate of electron-transfer reduction of O2 to O2.- in MeCN.
AB - Comparison of the catalytic effect of Mg2+ in reduction of O2 by 1,5-dihydroflavin anion with that in electron transfer from decamethylferrocene to O2 has revealed that the catalysis of Mg 2+ in both cases is ascribed to the 1: 1 and 1: 2 complexes formed between O2.- and Mg2+, which result in acceleration of the rate of electron-transfer reduction of O2 to O2.- in MeCN.
UR - http://www.scopus.com/inward/record.url?scp=37049089634&partnerID=8YFLogxK
U2 - 10.1039/C39940000521
DO - 10.1039/C39940000521
M3 - Article
AN - SCOPUS:37049089634
SN - 0022-4936
SP - 521
EP - 522
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 4
ER -