Blue transient complex formation in the electron-transfer reaction between iron(III) and a reduced nicotinamide-adenine dinucleotide analogue without an amide group

Shunichi Fukuzumi; Seiji Mochizuki; Toshio Tanaka

doi:10.1039/DT9900000695

Blue transient complex formation in the electron-transfer reaction between iron(III) and a reduced nicotinamide-adenine dinucleotide analogue without an amide group

Shunichi Fukuzumi, Seiji Mochizuki, Toshio Tanaka

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A blue transient complex with a stoicheiometry [Fe(C₁₃H ₁₀NMe)]³⁺ is formed very rapidly in the electron transfer from 9,10-dihydro-10-methylacridine (C₁₃H₁₀NMe) to Fe ³⁺ in acetonitrile at 298 K. The disappearance of the absorption band (λ_max. 640 nm) due to [Fe(C₁₃H₁₀NMe)] ³⁺ obeys pseudo-first-order kinetics, and is accompanied by the appearance of an absorption band (λ_max. 358 nm) due to the oxidized product, 10-methylacridinium ion (C₁₃H₉NMe ⁺).

Original language	English
Pages (from-to)	695-697
Number of pages	3
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	2
DOIs	https://doi.org/10.1039/DT9900000695
State	Published - 1990

Access to Document

10.1039/DT9900000695

Cite this

@article{44e9242d6a074b29a40f6f15bb3fbc55,

title = "Blue transient complex formation in the electron-transfer reaction between iron(III) and a reduced nicotinamide-adenine dinucleotide analogue without an amide group",

abstract = "A blue transient complex with a stoicheiometry [Fe(C13H 10NMe)]3+ is formed very rapidly in the electron transfer from 9,10-dihydro-10-methylacridine (C13H10NMe) to Fe 3+ in acetonitrile at 298 K. The disappearance of the absorption band (λmax. 640 nm) due to [Fe(C13H10NMe)] 3+ obeys pseudo-first-order kinetics, and is accompanied by the appearance of an absorption band (λmax. 358 nm) due to the oxidized product, 10-methylacridinium ion (C13H9NMe +).",

author = "Shunichi Fukuzumi and Seiji Mochizuki and Toshio Tanaka",

year = "1990",

doi = "10.1039/DT9900000695",

language = "English",

pages = "695--697",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

number = "2",

}

Blue transient complex formation in the electron-transfer reaction between iron(III) and a reduced nicotinamide-adenine dinucleotide analogue without an amide group. / Fukuzumi, Shunichi; Mochizuki, Seiji; Tanaka, Toshio.
In: Journal of the Chemical Society. Dalton Transactions, No. 2, 1990, p. 695-697.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Blue transient complex formation in the electron-transfer reaction between iron(III) and a reduced nicotinamide-adenine dinucleotide analogue without an amide group

AU - Fukuzumi, Shunichi

AU - Mochizuki, Seiji

AU - Tanaka, Toshio

PY - 1990

Y1 - 1990

N2 - A blue transient complex with a stoicheiometry [Fe(C13H 10NMe)]3+ is formed very rapidly in the electron transfer from 9,10-dihydro-10-methylacridine (C13H10NMe) to Fe 3+ in acetonitrile at 298 K. The disappearance of the absorption band (λmax. 640 nm) due to [Fe(C13H10NMe)] 3+ obeys pseudo-first-order kinetics, and is accompanied by the appearance of an absorption band (λmax. 358 nm) due to the oxidized product, 10-methylacridinium ion (C13H9NMe +).

AB - A blue transient complex with a stoicheiometry [Fe(C13H 10NMe)]3+ is formed very rapidly in the electron transfer from 9,10-dihydro-10-methylacridine (C13H10NMe) to Fe 3+ in acetonitrile at 298 K. The disappearance of the absorption band (λmax. 640 nm) due to [Fe(C13H10NMe)] 3+ obeys pseudo-first-order kinetics, and is accompanied by the appearance of an absorption band (λmax. 358 nm) due to the oxidized product, 10-methylacridinium ion (C13H9NMe +).

UR - https://www.scopus.com/pages/publications/37049089371

U2 - 10.1039/DT9900000695

DO - 10.1039/DT9900000695

M3 - Article

AN - SCOPUS:37049089371

SN - 1472-7773

SP - 695

EP - 697

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 2

ER -

Blue transient complex formation in the electron-transfer reaction between iron(III) and a reduced nicotinamide-adenine dinucleotide analogue without an amide group

Abstract

Access to Document

Fingerprint

Cite this