Bis[(2,2-dimethyl-1,3-propane-diamine-k 2N,N′)(piperidine-2-carboxylato-k2N,O)platinum(II)] sulfate

Rita Song; Kwan Mook Kim; Youn Soo Sohn

doi:10.1107/S0108270103025678

Bis[(2,2-dimethyl-1,3-propane-diamine-k ²N,N′)(piperidine-2-carboxylato-k²N,O)platinum(II)] sulfate

Rita Song, Kwan Mook Kim, Youn Soo Sohn

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The crystal structure of [Pt(C₆H₁₀NO ₂)(C₅H₁₄N ₂)]₂(SO ₄) with cations in the asymmetric unit was discussed. It was found that the two complex cations which exhibit a square-planar Pt¹¹ coordination were identical. It was observed that steric hindrance increased severly in the case of coordinated complex. Analysis suggests that the transformation of the neutral complex to the cationic complex was induced by the steric interaction.

Original language	English
Pages (from-to)	m555-m557
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	59
Issue number	12
DOIs	https://doi.org/10.1107/S0108270103025678
State	Published - Dec 2003

Access to Document

10.1107/S0108270103025678

Cite this

@article{48a16362ac8b4961b2eb6361f5b2ff98,

title = "Bis[(2,2-dimethyl-1,3-propane-diamine-k 2N,N′)(piperidine-2-carboxylato-k2N,O)platinum(II)] sulfate",

abstract = "The crystal structure of [Pt(C6H10NO 2)(C5H14N 2)]2(SO 4) with cations in the asymmetric unit was discussed. It was found that the two complex cations which exhibit a square-planar Pt11 coordination were identical. It was observed that steric hindrance increased severly in the case of coordinated complex. Analysis suggests that the transformation of the neutral complex to the cationic complex was induced by the steric interaction.",

author = "Rita Song and Kim, {Kwan Mook} and Sohn, {Youn Soo}",

year = "2003",

month = dec,

doi = "10.1107/S0108270103025678",

language = "English",

volume = "59",

pages = "m555--m557",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "12",

}

TY - JOUR

T1 - Bis[(2,2-dimethyl-1,3-propane-diamine-k 2N,N′)(piperidine-2-carboxylato-k2N,O)platinum(II)] sulfate

AU - Song, Rita

AU - Kim, Kwan Mook

AU - Sohn, Youn Soo

PY - 2003/12

Y1 - 2003/12

N2 - The crystal structure of [Pt(C6H10NO 2)(C5H14N 2)]2(SO 4) with cations in the asymmetric unit was discussed. It was found that the two complex cations which exhibit a square-planar Pt11 coordination were identical. It was observed that steric hindrance increased severly in the case of coordinated complex. Analysis suggests that the transformation of the neutral complex to the cationic complex was induced by the steric interaction.

AB - The crystal structure of [Pt(C6H10NO 2)(C5H14N 2)]2(SO 4) with cations in the asymmetric unit was discussed. It was found that the two complex cations which exhibit a square-planar Pt11 coordination were identical. It was observed that steric hindrance increased severly in the case of coordinated complex. Analysis suggests that the transformation of the neutral complex to the cationic complex was induced by the steric interaction.

UR - http://www.scopus.com/inward/record.url?scp=1642454760&partnerID=8YFLogxK

U2 - 10.1107/S0108270103025678

DO - 10.1107/S0108270103025678

M3 - Article

C2 - 14671358

AN - SCOPUS:1642454760

SN - 0108-2701

VL - 59

SP - m555-m557

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 12

ER -

Bis[(2,2-dimethyl-1,3-propane-diamine-k 2N,N′)(piperidine-2-carboxylato-k2N,O)platinum(II)] sulfate

Abstract

Access to Document

Fingerprint

Cite this

Bis[(2,2-dimethyl-1,3-propane-diamine-k ²N,N′)(piperidine-2-carboxylato-k²N,O)platinum(II)] sulfate