Biomimetic alkane hydroxylation by cobalt(III) porphyrin complex and m-chloroperbenzoic acid

W. Nam; I. Kim; Y. Kim; C. Kim

doi:10.1039/b103986p

Biomimetic alkane hydroxylation by cobalt(III) porphyrin complex and m-chloroperbenzoic acid

W. Nam, I. Kim, Y. Kim, C. Kim

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Abstract

The catalytic hydroxylation of alkanes by an electron-deficient cobalt(III) porphyrin complex and m-chloroperbenzoic acid yielded alcohols as major products with a high k_H/k_D value, > 99% retention of stereochemistry, and a high regioselectivity; a high-valent cobalt - oxo porphyrin complex was suggested as a reactive hydroxylating intermediate.

Original language	English
Pages (from-to)	1262-1263
Number of pages	2
Journal	Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/b103986p
State	Published - 21 Jul 2001

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title = "Biomimetic alkane hydroxylation by cobalt(III) porphyrin complex and m-chloroperbenzoic acid",

abstract = "The catalytic hydroxylation of alkanes by an electron-deficient cobalt(III) porphyrin complex and m-chloroperbenzoic acid yielded alcohols as major products with a high kH/kD value, > 99% retention of stereochemistry, and a high regioselectivity; a high-valent cobalt - oxo porphyrin complex was suggested as a reactive hydroxylating intermediate.",

author = "W. Nam and I. Kim and Y. Kim and C. Kim",

year = "2001",

month = jul,

day = "21",

doi = "10.1039/b103986p",

language = "English",

pages = "1262--1263",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Biomimetic alkane hydroxylation by cobalt(III) porphyrin complex and m-chloroperbenzoic acid

AU - Nam, W.

AU - Kim, I.

AU - Kim, Y.

AU - Kim, C.

PY - 2001/7/21

Y1 - 2001/7/21

N2 - The catalytic hydroxylation of alkanes by an electron-deficient cobalt(III) porphyrin complex and m-chloroperbenzoic acid yielded alcohols as major products with a high kH/kD value, > 99% retention of stereochemistry, and a high regioselectivity; a high-valent cobalt - oxo porphyrin complex was suggested as a reactive hydroxylating intermediate.

AB - The catalytic hydroxylation of alkanes by an electron-deficient cobalt(III) porphyrin complex and m-chloroperbenzoic acid yielded alcohols as major products with a high kH/kD value, > 99% retention of stereochemistry, and a high regioselectivity; a high-valent cobalt - oxo porphyrin complex was suggested as a reactive hydroxylating intermediate.

UR - http://www.scopus.com/inward/record.url?scp=0035928491&partnerID=8YFLogxK

U2 - 10.1039/b103986p

DO - 10.1039/b103986p

M3 - Article

AN - SCOPUS:0035928491

SN - 1359-7345

SP - 1262

EP - 1263

JO - Chemical Communications

JF - Chemical Communications

IS - 14

ER -

Biomimetic alkane hydroxylation by cobalt(III) porphyrin complex and m-chloroperbenzoic acid

Abstract

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