BINO l-based chiral receptors as fluorescent and colorimetric chemosensors for amino acids

Fang Wang; Raju Nandhakumar; Ying Hu; Dabin Kim; Kwan Mook Kim; Juyoung Yoon

doi:10.1021/jo401789a

BINO l-based chiral receptors as fluorescent and colorimetric chemosensors for amino acids

Fang Wang, Raju Nandhakumar, Ying Hu, Dabin Kim, Kwan Mook Kim, Juyoung Yoon

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

56 Scopus citations

Abstract

Three representative BINOL derivatives were examined for their chiral recognitions with d- and l-t-Boc-amino acid anions: an open system 1, which bears two urea groups and two pyrene groups; a closed ring system 2, which bears two urea groups with a closed ring system; and a dimeric system 3, which bears two benzylic amine groups and two pyrene groups. Dimeric system 3 displayed a ΔI_D/ΔI_L of 12.95 for t-Boc-alanine.

Original language	English
Pages (from-to)	11571-11576
Number of pages	6
Journal	Journal of Organic Chemistry
Volume	78
Issue number	22
DOIs	https://doi.org/10.1021/jo401789a
State	Published - 15 Nov 2013

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abstract = "Three representative BINOL derivatives were examined for their chiral recognitions with d- and l-t-Boc-amino acid anions: an open system 1, which bears two urea groups and two pyrene groups; a closed ring system 2, which bears two urea groups with a closed ring system; and a dimeric system 3, which bears two benzylic amine groups and two pyrene groups. Dimeric system 3 displayed a ΔID/ΔIL of 12.95 for t-Boc-alanine.",

author = "Fang Wang and Raju Nandhakumar and Ying Hu and Dabin Kim and Kim, {Kwan Mook} and Juyoung Yoon",

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AU - Wang, Fang

AU - Nandhakumar, Raju

AU - Hu, Ying

AU - Kim, Dabin

AU - Kim, Kwan Mook

AU - Yoon, Juyoung

PY - 2013/11/15

Y1 - 2013/11/15

N2 - Three representative BINOL derivatives were examined for their chiral recognitions with d- and l-t-Boc-amino acid anions: an open system 1, which bears two urea groups and two pyrene groups; a closed ring system 2, which bears two urea groups with a closed ring system; and a dimeric system 3, which bears two benzylic amine groups and two pyrene groups. Dimeric system 3 displayed a ΔID/ΔIL of 12.95 for t-Boc-alanine.

AB - Three representative BINOL derivatives were examined for their chiral recognitions with d- and l-t-Boc-amino acid anions: an open system 1, which bears two urea groups and two pyrene groups; a closed ring system 2, which bears two urea groups with a closed ring system; and a dimeric system 3, which bears two benzylic amine groups and two pyrene groups. Dimeric system 3 displayed a ΔID/ΔIL of 12.95 for t-Boc-alanine.

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 22

ER -

BINO l-based chiral receptors as fluorescent and colorimetric chemosensors for amino acids

Abstract

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