Autocatalytic dioxygen activation to produce an iron(v)-oxo complex without any reductants

Muniyandi Sankaralingam, Yong Min Lee, Xiaoyan Lu, Anil Kumar Vardhaman, Wonwoo Nam, Shunichi Fukuzumi

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

An iron(v)-oxo complex with a tetraamido macrocyclic ligand, [(TAML)FeV(O)]-, was produced by reacting [(TAML)FeIII]- with dioxygen without any electron source in acetone at 298 K. The autocatalytic mechanism of dioxygen activation for the formation of an iron(v)-oxo complex has been clarified based on the autocatalysis by radical chain initiators.

Original languageEnglish
Pages (from-to)8348-8351
Number of pages4
JournalChemical Communications
Volume53
Issue number59
DOIs
StatePublished - 2017

Fingerprint

Dive into the research topics of 'Autocatalytic dioxygen activation to produce an iron(v)-oxo complex without any reductants'. Together they form a unique fingerprint.

Cite this