@article{fef5b8bc501b485a932553f66290914d,
title = "Autocatalytic dioxygen activation to produce an iron(v)-oxo complex without any reductants",
abstract = "An iron(v)-oxo complex with a tetraamido macrocyclic ligand, [(TAML)FeV(O)]-, was produced by reacting [(TAML)FeIII]- with dioxygen without any electron source in acetone at 298 K. The autocatalytic mechanism of dioxygen activation for the formation of an iron(v)-oxo complex has been clarified based on the autocatalysis by radical chain initiators.",
author = "Muniyandi Sankaralingam and Lee, {Yong Min} and Xiaoyan Lu and Vardhaman, {Anil Kumar} and Wonwoo Nam and Shunichi Fukuzumi",
note = "Funding Information: This work was supported by the NRF of Korea through CRI (NRF-2012R1A3A2048842 to W. N.) and GRL (NRF-2010-00353 to W. N.), and a Grant-in-Aid (no. 16H02268 to S. F.) from the Ministry of Education, Culture, Sports, Science and Technology (MEXT), and a SENTAN project from the Japan Science and Technology Agency (JST). Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",
year = "2017",
doi = "10.1039/c7cc03742b",
language = "English",
volume = "53",
pages = "8348--8351",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "59",
}