Assembly and stepwise oxidation of interpenetrated coordination cages based on phenothiazine

Marina Frank; Jakob Hey; Ilker Balcioglu; Yu Sheng Chen; Dietmar Stalke; Tomoyoshi Suenobu; Shunichi Fukuzumi; Holm Frauendorf; Guido H. Clever

doi:10.1002/anie.201302536

Assembly and stepwise oxidation of interpenetrated coordination cages based on phenothiazine

Marina Frank
, Jakob Hey
, Ilker Balcioglu
, Yu Sheng Chen
, Dietmar Stalke
, Tomoyoshi Suenobu
, Shunichi Fukuzumi
, Holm Frauendorf
, Guido H. Clever

Department of Chemistry & Nanoscience

Research output: Contribution to journal › Article › peer-review

106 Scopus citations

Abstract

A breath of fresh air is sufficient for the eightfold S-monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square-planar-coordinated Pd^II cations. Besides these two cages, which were both characterized by X-ray crystallography, an eightfold S-dioxygenated double-cage was obtained under harsher oxidation conditions.

Original language	English
Pages (from-to)	10102-10106
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	38
DOIs	https://doi.org/10.1002/anie.201302536
State	Published - 16 Sep 2013

Keywords

cage compounds
interpenetration
phenothiazines
redox chemistry
supramolecular chemistry

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10.1002/anie.201302536

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title = "Assembly and stepwise oxidation of interpenetrated coordination cages based on phenothiazine",

abstract = "A breath of fresh air is sufficient for the eightfold S-monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square-planar-coordinated PdII cations. Besides these two cages, which were both characterized by X-ray crystallography, an eightfold S-dioxygenated double-cage was obtained under harsher oxidation conditions.",

keywords = "cage compounds, interpenetration, phenothiazines, redox chemistry, supramolecular chemistry",

author = "Marina Frank and Jakob Hey and Ilker Balcioglu and Chen, \{Yu Sheng\} and Dietmar Stalke and Tomoyoshi Suenobu and Shunichi Fukuzumi and Holm Frauendorf and Clever, \{Guido H.\}",

year = "2013",

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doi = "10.1002/anie.201302536",

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T1 - Assembly and stepwise oxidation of interpenetrated coordination cages based on phenothiazine

AU - Frank, Marina

AU - Hey, Jakob

AU - Balcioglu, Ilker

AU - Chen, Yu Sheng

AU - Stalke, Dietmar

AU - Suenobu, Tomoyoshi

AU - Fukuzumi, Shunichi

AU - Frauendorf, Holm

AU - Clever, Guido H.

PY - 2013/9/16

Y1 - 2013/9/16

N2 - A breath of fresh air is sufficient for the eightfold S-monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square-planar-coordinated PdII cations. Besides these two cages, which were both characterized by X-ray crystallography, an eightfold S-dioxygenated double-cage was obtained under harsher oxidation conditions.

AB - A breath of fresh air is sufficient for the eightfold S-monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square-planar-coordinated PdII cations. Besides these two cages, which were both characterized by X-ray crystallography, an eightfold S-dioxygenated double-cage was obtained under harsher oxidation conditions.

KW - cage compounds

KW - interpenetration

KW - phenothiazines

KW - redox chemistry

KW - supramolecular chemistry

UR - https://www.scopus.com/pages/publications/84884264920

U2 - 10.1002/anie.201302536

DO - 10.1002/anie.201302536

M3 - Article

C2 - 23881819

AN - SCOPUS:84884264920

SN - 1433-7851

VL - 52

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EP - 10106

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 38

ER -

Assembly and stepwise oxidation of interpenetrated coordination cages based on phenothiazine

Abstract

Keywords

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